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Strategic Approaches to the Dendritic Growth and Interfacial Reaction of Lithium Metal Anode

Journal Article


Abstract


  • Utilization of lithium (Li) metal anode is highly desirable for achieving high energy density batteries. Even so, the unavoidable features of Li dendritic growth and inactive Li are still the main factors that hinder its practical application. During plating and stripping, the solid electrolyte interphase (SEI) layer can provide passivation, playing an important role in preventing direct contact between the electrolyte and the electrode in Li metal batteries. Because of complexities of the electrolyte chemical and electrochemical reactions, the various formation mechanisms for the SEI are still not well understood. What we do know is that a strategic artificial SEI achieved through additives electrolyte can suppress the Li dendrites. Otherwise, the dendrites keep generating an abundance of irreversible Li, resulting in severe capacity loss, internal short-circuiting, and cell failure. In this minireview, we focus on the phenomenon of dendritic Li-growth and provide a brief overview of SEI formation. We finally provide some clear insights and perspectives toward practical application of Li metal batteries.

UOW Authors


  •   Qutaish, Hamzeh (external author)
  •   Han, Sanga (external author)
  •   Kim, Jung Ho

Publication Date


  • 2021

Citation


  • Han, S. A., Qutaish, H., Park, M. S., Moon, J., & Kim, J. H. (2021). Strategic Approaches to the Dendritic Growth and Interfacial Reaction of Lithium Metal Anode. Chemistry - An Asian Journal, 16(24), 4010-4017. doi:10.1002/asia.202101108

Scopus Eid


  • 2-s2.0-85118938695

Start Page


  • 4010

End Page


  • 4017

Volume


  • 16

Issue


  • 24

Abstract


  • Utilization of lithium (Li) metal anode is highly desirable for achieving high energy density batteries. Even so, the unavoidable features of Li dendritic growth and inactive Li are still the main factors that hinder its practical application. During plating and stripping, the solid electrolyte interphase (SEI) layer can provide passivation, playing an important role in preventing direct contact between the electrolyte and the electrode in Li metal batteries. Because of complexities of the electrolyte chemical and electrochemical reactions, the various formation mechanisms for the SEI are still not well understood. What we do know is that a strategic artificial SEI achieved through additives electrolyte can suppress the Li dendrites. Otherwise, the dendrites keep generating an abundance of irreversible Li, resulting in severe capacity loss, internal short-circuiting, and cell failure. In this minireview, we focus on the phenomenon of dendritic Li-growth and provide a brief overview of SEI formation. We finally provide some clear insights and perspectives toward practical application of Li metal batteries.

UOW Authors


  •   Qutaish, Hamzeh (external author)
  •   Han, Sanga (external author)
  •   Kim, Jung Ho

Publication Date


  • 2021

Citation


  • Han, S. A., Qutaish, H., Park, M. S., Moon, J., & Kim, J. H. (2021). Strategic Approaches to the Dendritic Growth and Interfacial Reaction of Lithium Metal Anode. Chemistry - An Asian Journal, 16(24), 4010-4017. doi:10.1002/asia.202101108

Scopus Eid


  • 2-s2.0-85118938695

Start Page


  • 4010

End Page


  • 4017

Volume


  • 16

Issue


  • 24