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Magnetic hybrid organic-inorganic perovskite (CH3NH3)2XCl4(X = Mn, Cu, Co) crystals

Journal Article


Abstract


  • For the hybrid organic-inorganic perovskites with the general formula of A2MIIX4(A = methylammonium; MII= Mn, Cu and Co; X = Cl), the arrangement of metal ions and organic ligands leads to a delicate balance of space, spin and charge, which results in diverse properties. In this paper, we reported a group of hybrid organic-inorganic perovskite single crystals of (CH3NH3)2MnCl4, (CH3NH3)2CuCl4and (CH3NH3)2CoCl4grown by a simple solution evaporation method. Magnetic measurements show that all the single crystals display magnetic ordering at low temperature. Our results reveal a novel group of hybrid organic-inorganic magnetic perovskites.

Publication Date


  • 2021

Citation


  • Zhao, H., Fu, H., Hu, Z., Fu, Q., Tao, H., Weng, J., . . . Cheng, Z. (2021). Magnetic hybrid organic-inorganic perovskite (CH3NH3)2XCl4(X = Mn, Cu, Co) crystals. CrystEngComm, 23(30), 5208-5213. doi:10.1039/d1ce00679g

Scopus Eid


  • 2-s2.0-85111902332

Start Page


  • 5208

End Page


  • 5213

Volume


  • 23

Issue


  • 30

Abstract


  • For the hybrid organic-inorganic perovskites with the general formula of A2MIIX4(A = methylammonium; MII= Mn, Cu and Co; X = Cl), the arrangement of metal ions and organic ligands leads to a delicate balance of space, spin and charge, which results in diverse properties. In this paper, we reported a group of hybrid organic-inorganic perovskite single crystals of (CH3NH3)2MnCl4, (CH3NH3)2CuCl4and (CH3NH3)2CoCl4grown by a simple solution evaporation method. Magnetic measurements show that all the single crystals display magnetic ordering at low temperature. Our results reveal a novel group of hybrid organic-inorganic magnetic perovskites.

Publication Date


  • 2021

Citation


  • Zhao, H., Fu, H., Hu, Z., Fu, Q., Tao, H., Weng, J., . . . Cheng, Z. (2021). Magnetic hybrid organic-inorganic perovskite (CH3NH3)2XCl4(X = Mn, Cu, Co) crystals. CrystEngComm, 23(30), 5208-5213. doi:10.1039/d1ce00679g

Scopus Eid


  • 2-s2.0-85111902332

Start Page


  • 5208

End Page


  • 5213

Volume


  • 23

Issue


  • 30