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A novel pentamanganese(II) cluster produced by a controlled self assembly process; an exact match between the coordination algorithm of the metals and the ligand binding site arrangement

Journal Article


Abstract


  • The tetradentate ligand phaap combines a bridging alkoxide oxygen and diazine and pyridine nitrogen donors, with five critically positioned binding sites, and on reaction with Mn(ClO4)2·6H2O undergoes a controlled self assembly to produce a unique trigonal bipyramidal oxygen bridged metal cluster with an exact match between the coordination requirements of the five six-coordinate metals and the donor arrangements of the six coordinated ligands.

Publication Date


  • 1999

Citation


  • Matthews, C. J., Xu, Z., Mandal, S. K., Thompson, L. K., Biradha, K., Poirier, K., & Zaworotko, M. J. (1999). A novel pentamanganese(II) cluster produced by a controlled self assembly process; an exact match between the coordination algorithm of the metals and the ligand binding site arrangement. Chemical Communications, (4), 347-348. doi:10.1039/a808970a

Scopus Eid


  • 2-s2.0-0033590694

Web Of Science Accession Number


Start Page


  • 347

End Page


  • 348

Issue


  • 4

Abstract


  • The tetradentate ligand phaap combines a bridging alkoxide oxygen and diazine and pyridine nitrogen donors, with five critically positioned binding sites, and on reaction with Mn(ClO4)2·6H2O undergoes a controlled self assembly to produce a unique trigonal bipyramidal oxygen bridged metal cluster with an exact match between the coordination requirements of the five six-coordinate metals and the donor arrangements of the six coordinated ligands.

Publication Date


  • 1999

Citation


  • Matthews, C. J., Xu, Z., Mandal, S. K., Thompson, L. K., Biradha, K., Poirier, K., & Zaworotko, M. J. (1999). A novel pentamanganese(II) cluster produced by a controlled self assembly process; an exact match between the coordination algorithm of the metals and the ligand binding site arrangement. Chemical Communications, (4), 347-348. doi:10.1039/a808970a

Scopus Eid


  • 2-s2.0-0033590694

Web Of Science Accession Number


Start Page


  • 347

End Page


  • 348

Issue


  • 4