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A self-assembled novel octanuclear Cu(II) `pin-wheel¿ cluster exhibiting ferromagnetic coupling

Journal Article


Abstract


  • The heptadentate, “tritopic” ligand 2poapH2 reacts with Cu(NO3)2 in the presence of Gd(NO3)3 to give a novel, self-assembled, ferromagnetically coupled, alkoxide bridged octanuclear Cu(II) cluster in the shape of a pin-wheel, with a central Cu4[μ-O4] core, and isolated Curie-like [Gd(NO3)4(H2O)2]− anions. © 2001 The Royal Society of Chemistry.

Publication Date


  • 2001

Citation


  • Xu, Z., Thompson, L. K., & Miller, D. O. (2001). A self-assembled novel octanuclear Cu(II) `pin-wheel¿ cluster exhibiting ferromagnetic coupling. Chemical Communications, 1(13), 1170-1171. doi:10.1039/b101966j

Scopus Eid


  • 2-s2.0-0035822401

Web Of Science Accession Number


Start Page


  • 1170

End Page


  • 1171

Volume


  • 1

Issue


  • 13

Abstract


  • The heptadentate, “tritopic” ligand 2poapH2 reacts with Cu(NO3)2 in the presence of Gd(NO3)3 to give a novel, self-assembled, ferromagnetically coupled, alkoxide bridged octanuclear Cu(II) cluster in the shape of a pin-wheel, with a central Cu4[μ-O4] core, and isolated Curie-like [Gd(NO3)4(H2O)2]− anions. © 2001 The Royal Society of Chemistry.

Publication Date


  • 2001

Citation


  • Xu, Z., Thompson, L. K., & Miller, D. O. (2001). A self-assembled novel octanuclear Cu(II) `pin-wheel¿ cluster exhibiting ferromagnetic coupling. Chemical Communications, 1(13), 1170-1171. doi:10.1039/b101966j

Scopus Eid


  • 2-s2.0-0035822401

Web Of Science Accession Number


Start Page


  • 1170

End Page


  • 1171

Volume


  • 1

Issue


  • 13