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Electron spin resonance spectra and structures of the butylchlorotin derivatives of butane-2,3-semidione, BunCl3-nSnOCMeCMeO

Journal Article


Abstract


  • The ESR spectra of the radicals BunCl3-SnOCMeCMeO. are interpreted to imply that when n = 0 or 1, the biacetyl acts as a cis-bidentate ligand. When n = 2 it is (probably cis) monodentate When n = 3 it can act as both a cis- and a trans-monodentate Ligand; the former is rapidly fluxional and the latter is more slowly fluxional on the ESR time scale. © 1980.

Publication Date


  • 1980

Citation


  • J. Barker, P., G. Davies, A., & A.-A. Hawahari, J. (1980). Electron spin resonance spectra and structures of the butylchlorotin derivatives of butane-2,3-semidione, BunCl3-nSnOCMeCMeO. Journal of Organometallic Chemistry, 187(1). doi:10.1016/S0022-328X(00)90545-X

Scopus Eid


  • 2-s2.0-49149148272

Web Of Science Accession Number


Volume


  • 187

Issue


  • 1

Abstract


  • The ESR spectra of the radicals BunCl3-SnOCMeCMeO. are interpreted to imply that when n = 0 or 1, the biacetyl acts as a cis-bidentate ligand. When n = 2 it is (probably cis) monodentate When n = 3 it can act as both a cis- and a trans-monodentate Ligand; the former is rapidly fluxional and the latter is more slowly fluxional on the ESR time scale. © 1980.

Publication Date


  • 1980

Citation


  • J. Barker, P., G. Davies, A., & A.-A. Hawahari, J. (1980). Electron spin resonance spectra and structures of the butylchlorotin derivatives of butane-2,3-semidione, BunCl3-nSnOCMeCMeO. Journal of Organometallic Chemistry, 187(1). doi:10.1016/S0022-328X(00)90545-X

Scopus Eid


  • 2-s2.0-49149148272

Web Of Science Accession Number


Volume


  • 187

Issue


  • 1