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Tris(3,5-dimethyl-1H-pyrazole-kN 2)(pyridine-2,6-dicarboxyl-ato- k3 O 2,N,O 6)cobalt(II) monohydrate

Journal Article


Abstract


  • The reaction of Co(NO3)2·3H2O with pyridine-2,6-dicarboxylic acid and 3,5-dimethyl-1H-pyrazole in a 1:1:3 molar ratio affords the title complex, [Co(C7H3NO 4)(C5H8N2)3] ·H2O. The CoII atom is coordinated by one pyridine-2,6-dicarboxyl-ate chelating ligand and three 3,5-dimethyl-1H-pyrazole ligands in a distorted octa-hedral geometry. Hydrogen-bonding interactions involving the coordinated carboxylate group, 3,5-dimethyl-1H-pyrazole and water help to consolidate the crystal structure © 2009.

Publication Date


  • 2009

Citation


  • Lin, K. H., Yu, Z. Y., Zhong, Y. H., & Shao, M. (2009). Tris(3,5-dimethyl-1H-pyrazole-kN 2)(pyridine-2,6-dicarboxyl-ato- k3 O 2,N,O 6)cobalt(II) monohydrate. Acta Crystallographica Section E: Structure Reports Online, 65(4). doi:10.1107/S1600536809010538

Scopus Eid


  • 2-s2.0-64149131606

Web Of Science Accession Number


Volume


  • 65

Issue


  • 4

Abstract


  • The reaction of Co(NO3)2·3H2O with pyridine-2,6-dicarboxylic acid and 3,5-dimethyl-1H-pyrazole in a 1:1:3 molar ratio affords the title complex, [Co(C7H3NO 4)(C5H8N2)3] ·H2O. The CoII atom is coordinated by one pyridine-2,6-dicarboxyl-ate chelating ligand and three 3,5-dimethyl-1H-pyrazole ligands in a distorted octa-hedral geometry. Hydrogen-bonding interactions involving the coordinated carboxylate group, 3,5-dimethyl-1H-pyrazole and water help to consolidate the crystal structure © 2009.

Publication Date


  • 2009

Citation


  • Lin, K. H., Yu, Z. Y., Zhong, Y. H., & Shao, M. (2009). Tris(3,5-dimethyl-1H-pyrazole-kN 2)(pyridine-2,6-dicarboxyl-ato- k3 O 2,N,O 6)cobalt(II) monohydrate. Acta Crystallographica Section E: Structure Reports Online, 65(4). doi:10.1107/S1600536809010538

Scopus Eid


  • 2-s2.0-64149131606

Web Of Science Accession Number


Volume


  • 65

Issue


  • 4