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E.S.R. identification of alkoxythiocarbonyl radicals as possible intermediates in Barton deoxygenation of alcohols

Journal Article


Abstract


  • O-Alkyl S-methyl dithiocarbonates react with trimethyltin radicals to afford alkoxythiocarbonyl radicals which undergo slow β-fission to alkyl radicals and carbon oxysulphide.

Publication Date


  • 1984

Citation


  • Barker, P. J., & Beckwith, A. L. J. (1984). E.S.R. identification of alkoxythiocarbonyl radicals as possible intermediates in Barton deoxygenation of alcohols. Journal of the Chemical Society, Chemical Communications, (11), 683-684. doi:10.1039/c39840000683

Scopus Eid


  • 2-s2.0-37049097820

Start Page


  • 683

End Page


  • 684

Issue


  • 11

Abstract


  • O-Alkyl S-methyl dithiocarbonates react with trimethyltin radicals to afford alkoxythiocarbonyl radicals which undergo slow β-fission to alkyl radicals and carbon oxysulphide.

Publication Date


  • 1984

Citation


  • Barker, P. J., & Beckwith, A. L. J. (1984). E.S.R. identification of alkoxythiocarbonyl radicals as possible intermediates in Barton deoxygenation of alcohols. Journal of the Chemical Society, Chemical Communications, (11), 683-684. doi:10.1039/c39840000683

Scopus Eid


  • 2-s2.0-37049097820

Start Page


  • 683

End Page


  • 684

Issue


  • 11