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Effect of preoxidation and sintering on properties of ilmenite concentrates

Journal Article


Abstract


  • The paper examines the effects of preoxidation and sintering on the phase composition, specific surface area, morphology and reducibility of ilmenite concentrates. Samples were preoxidised in air or sintered in argon by temperature-programmed heating to temperatures of 600-1400°C at a ramping rate of 300°C/h. In the concentrates preoxidised at temperatures up to 800°C, ilmenite formed an intermediate product, Fe2O3·2TiO2, which decomposed into Fe2O3 and TiO2. At temperatures above 800°C, pseudorutile was transformed into ferric pseudobrookite and rutile. Haematite recombined with rutile to form pseudobrookite at temperatures above 1000°C. When samples were heated in an argon atmosphere, ferric-ferrous pseudobrookite solid solution was formed from ilmenite and pseudorutile. Preoxidation and sintering at temperatures above 600°C caused a sharp decrease in the specific surface area of samples. The specific surface area decreased by more than 97% when samples were heated to 1200°C. Preoxidation enhanced while sintering retarded the reduction of iron oxides in ilmenite concentrates by methane-hydrogen gas mixtures in the temperature range of 550-800°C. Both preoxidation and sintering increased the temperature required to reduce titanium oxides. At high temperatures, such as 1200°C, the effects of preoxidation and sintering on isothermal reduction of ilmenites were negligible. © 2002 Elsevier Science B.V. All rights reserved.

Publication Date


  • 2002

Citation


  • Zhang, G., & Ostrovski, O. (2002). Effect of preoxidation and sintering on properties of ilmenite concentrates. International Journal of Mineral Processing, 64(4), 201-218. doi:10.1016/S0301-7516(01)00055-2

Scopus Eid


  • 2-s2.0-0036537881

Start Page


  • 201

End Page


  • 218

Volume


  • 64

Issue


  • 4

Abstract


  • The paper examines the effects of preoxidation and sintering on the phase composition, specific surface area, morphology and reducibility of ilmenite concentrates. Samples were preoxidised in air or sintered in argon by temperature-programmed heating to temperatures of 600-1400°C at a ramping rate of 300°C/h. In the concentrates preoxidised at temperatures up to 800°C, ilmenite formed an intermediate product, Fe2O3·2TiO2, which decomposed into Fe2O3 and TiO2. At temperatures above 800°C, pseudorutile was transformed into ferric pseudobrookite and rutile. Haematite recombined with rutile to form pseudobrookite at temperatures above 1000°C. When samples were heated in an argon atmosphere, ferric-ferrous pseudobrookite solid solution was formed from ilmenite and pseudorutile. Preoxidation and sintering at temperatures above 600°C caused a sharp decrease in the specific surface area of samples. The specific surface area decreased by more than 97% when samples were heated to 1200°C. Preoxidation enhanced while sintering retarded the reduction of iron oxides in ilmenite concentrates by methane-hydrogen gas mixtures in the temperature range of 550-800°C. Both preoxidation and sintering increased the temperature required to reduce titanium oxides. At high temperatures, such as 1200°C, the effects of preoxidation and sintering on isothermal reduction of ilmenites were negligible. © 2002 Elsevier Science B.V. All rights reserved.

Publication Date


  • 2002

Citation


  • Zhang, G., & Ostrovski, O. (2002). Effect of preoxidation and sintering on properties of ilmenite concentrates. International Journal of Mineral Processing, 64(4), 201-218. doi:10.1016/S0301-7516(01)00055-2

Scopus Eid


  • 2-s2.0-0036537881

Start Page


  • 201

End Page


  • 218

Volume


  • 64

Issue


  • 4