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Synthesis and complexes of the first chelating ligand containing a 1,2-benzisoxazole subunit

Journal Article


Abstract


  • The new ligand 3-(2-pyridyl)-1,2-benzisoxazole (3) was prepared in five steps from readily available starting materials. It represents the first example of a chelating ligand containing a 1,2-benzisoxazole group and readily forms complexes with palladium(II), copper(II) and ruthenium(II). An X-ray crystal structure of the copper complex, trans-Cu(3)2(NO3)2, is the first reported structure of a complex containing a 1,2-benzisoxazole. (C) 2000 Elsevier Science S.A.

Publication Date


  • 2000

Citation


  • Richardson, C., & J. Steel, P. (2000). Synthesis and complexes of the first chelating ligand containing a 1,2-benzisoxazole subunit. Inorganic Chemistry Communications, 3(4), 155-158. doi:10.1016/S1387-7003(00)00031-9

Scopus Eid


  • 2-s2.0-0033826332

Start Page


  • 155

End Page


  • 158

Volume


  • 3

Issue


  • 4

Abstract


  • The new ligand 3-(2-pyridyl)-1,2-benzisoxazole (3) was prepared in five steps from readily available starting materials. It represents the first example of a chelating ligand containing a 1,2-benzisoxazole group and readily forms complexes with palladium(II), copper(II) and ruthenium(II). An X-ray crystal structure of the copper complex, trans-Cu(3)2(NO3)2, is the first reported structure of a complex containing a 1,2-benzisoxazole. (C) 2000 Elsevier Science S.A.

Publication Date


  • 2000

Citation


  • Richardson, C., & J. Steel, P. (2000). Synthesis and complexes of the first chelating ligand containing a 1,2-benzisoxazole subunit. Inorganic Chemistry Communications, 3(4), 155-158. doi:10.1016/S1387-7003(00)00031-9

Scopus Eid


  • 2-s2.0-0033826332

Start Page


  • 155

End Page


  • 158

Volume


  • 3

Issue


  • 4