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Intramolecular interception of the Newman-Kwart rearrangement by carboxylic acids

Journal Article


Abstract


  • Instead of undergoing the Newman-Kwart rearrangement, thermally-promoted reactions of O-aryl dimethylthiocarbamates featuring ortho-carboxylic acid substituents result in the loss of carbonylsulfide and formation of N,N-dimethylsalicylamides in high yields.

Publication Date


  • 2020

Citation


  • Ablott, T. A., Fishburn, M. G., Turner, D. R., & Richardson, C. (2020). Intramolecular interception of the Newman-Kwart rearrangement by carboxylic acids. Tetrahedron Letters, 61(30). doi:10.1016/j.tetlet.2020.152153

Scopus Eid


  • 2-s2.0-85086935533

Volume


  • 61

Issue


  • 30

Abstract


  • Instead of undergoing the Newman-Kwart rearrangement, thermally-promoted reactions of O-aryl dimethylthiocarbamates featuring ortho-carboxylic acid substituents result in the loss of carbonylsulfide and formation of N,N-dimethylsalicylamides in high yields.

Publication Date


  • 2020

Citation


  • Ablott, T. A., Fishburn, M. G., Turner, D. R., & Richardson, C. (2020). Intramolecular interception of the Newman-Kwart rearrangement by carboxylic acids. Tetrahedron Letters, 61(30). doi:10.1016/j.tetlet.2020.152153

Scopus Eid


  • 2-s2.0-85086935533

Volume


  • 61

Issue


  • 30