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Mixed donor, phenanthroline photoactive MOFs with favourable CO2selectivity

Journal Article


Abstract


  • Mixed donor phenanthroline-carboxylate linkers were combined with MnII or ZnII to form photoactive MOFs with large pore apertures. The MOFs display high CO2 adsorption capacities, which consequently causes structural framework flexibility, and align with favorable metrics for selective CO2 capture. The photophysical properties of the MOFs were investigated, with the MnII MOF giving rise to short triplet LMCT lifetimes. This journal is

Publication Date


  • 2020

Citation


  • Setter, C. J., Price, M. B., Conte, L., Schmitt, W., Batten, S. R., Richardson, C., . . . MacReadie, L. K. (2020). Mixed donor, phenanthroline photoactive MOFs with favourable CO2selectivity. Chemical Communications, 56(87), 13377-13380. doi:10.1039/d0cc05715k

Scopus Eid


  • 2-s2.0-85095461889

Start Page


  • 13377

End Page


  • 13380

Volume


  • 56

Issue


  • 87

Abstract


  • Mixed donor phenanthroline-carboxylate linkers were combined with MnII or ZnII to form photoactive MOFs with large pore apertures. The MOFs display high CO2 adsorption capacities, which consequently causes structural framework flexibility, and align with favorable metrics for selective CO2 capture. The photophysical properties of the MOFs were investigated, with the MnII MOF giving rise to short triplet LMCT lifetimes. This journal is

Publication Date


  • 2020

Citation


  • Setter, C. J., Price, M. B., Conte, L., Schmitt, W., Batten, S. R., Richardson, C., . . . MacReadie, L. K. (2020). Mixed donor, phenanthroline photoactive MOFs with favourable CO2selectivity. Chemical Communications, 56(87), 13377-13380. doi:10.1039/d0cc05715k

Scopus Eid


  • 2-s2.0-85095461889

Start Page


  • 13377

End Page


  • 13380

Volume


  • 56

Issue


  • 87