Asymmetric Conjugate Addition of Organometallic Reagents to Chiral Vinyl Sulfoximines

Citation

• Pyne, S. G. (1986). Asymmetric Conjugate Addition of Organometallic Reagents to Chiral Vinyl Sulfoximines. Journal of Organic Chemistry, 51(1), 81-87. doi:10.1021/jo00351a017

Digital Object Identifier (doi)

• 10.1021/jo00351a017

Scopus Eid

• 2-s2.0-33845374042

Web Of Science Accession Number

Start Page

• 81

End Page

• 87

Volume

• 51

Issue

• 1

Abstract

• The chiral vinyl sulfoximines 1 and 2 (R‘ = C6H5, CH3,n-Bu, C6H5CH2CH2) have been prepared; they undergo conjugate addition reactions with organometallic reagents with high asymmetric induction. These conjugate addition adducts have been converted to chiral 3-alkylalkanoic acids in high enantiomeric excess (>90%). © 1986, American Chemical Society. All rights reserved.

UOW Authors

•   Pyne, Stephen

Publication Date

• 1986

Publisher

• American Chemical Society (ACS) 

Published In

• Journal of Organic Chemistry  Journal

Citation

• Pyne, S. G. (1986). Asymmetric Conjugate Addition of Organometallic Reagents to Chiral Vinyl Sulfoximines. Journal of Organic Chemistry, 51(1), 81-87. doi:10.1021/jo00351a017

Digital Object Identifier (doi)

• 10.1021/jo00351a017

Scopus Eid

• 2-s2.0-33845374042

Web Of Science Accession Number

Start Page

• 81

End Page

• 87

Volume

• 51

Issue

• 1