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Synthesis of N,N-Bis[tricarbonyl(cyclohexa-2,4-diene)] Amine and Ammonium Complexes

Journal Article


Abstract


  • The synthesis and characterisation of the novel products [(CO)3Fe(diene-NH2-diene)Fe(CO)3]+ and [(CO)3Fe(diene-NH-diene)Fe(CO)3] from the reaction of the tricarbonyl(η5-dienyl)iron cationic complexes 1 and 2 with ammonia are reported; this contrasts with the anlogous reactions of these cations with primary and secondary amines which lead only to mono-addition products.

Publication Date


  • 1996

Citation


  • Siu, A. F. H., Kane-Maguire, L. A. P., Pyne, S. G., & Lambrecht, R. M. (1996). Synthesis of N,N-Bis[tricarbonyl(cyclohexa-2,4-diene)] Amine and Ammonium Complexes. Journal of Chemical Research - Part S, (9), 395.

Scopus Eid


  • 2-s2.0-2742598169

Web Of Science Accession Number


Start Page


  • 395

Issue


  • 9

Abstract


  • The synthesis and characterisation of the novel products [(CO)3Fe(diene-NH2-diene)Fe(CO)3]+ and [(CO)3Fe(diene-NH-diene)Fe(CO)3] from the reaction of the tricarbonyl(η5-dienyl)iron cationic complexes 1 and 2 with ammonia are reported; this contrasts with the anlogous reactions of these cations with primary and secondary amines which lead only to mono-addition products.

Publication Date


  • 1996

Citation


  • Siu, A. F. H., Kane-Maguire, L. A. P., Pyne, S. G., & Lambrecht, R. M. (1996). Synthesis of N,N-Bis[tricarbonyl(cyclohexa-2,4-diene)] Amine and Ammonium Complexes. Journal of Chemical Research - Part S, (9), 395.

Scopus Eid


  • 2-s2.0-2742598169

Web Of Science Accession Number


Start Page


  • 395

Issue


  • 9