Abstract
-
The reduction of β-substituted-γ-keto N-tosyl sulfoximines is highly diastereoselective and the allylic sulfoximines products undergo a facile rearrangement to allylic sulfinamides in the presence of a palladium(0) catalyst.
The reduction of β-substituted-γ-keto N-tosyl sulfoximines is highly diastereoselective and the allylic sulfoximines products undergo a facile rearrangement to allylic sulfinamides in the presence of a palladium(0) catalyst.
The reduction of β-substituted-γ-keto N-tosyl sulfoximines is highly diastereoselective and the allylic sulfoximines products undergo a facile rearrangement to allylic sulfinamides in the presence of a palladium(0) catalyst.