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Diastereoselective reductions of ß-substituted-¿-keto sulfoximines and a novel palladium(0)-catalysed allylic sulfoximine to allylic sulfinamide rearrangement

Journal Article


Abstract


  • The reduction of β-substituted-γ-keto N-tosyl sulfoximines is highly diastereoselective and the allylic sulfoximines products undergo a facile rearrangement to allylic sulfinamides in the presence of a palladium(0) catalyst.

Publication Date


  • 1995

Citation


  • Pyne, S. G., Dong, Z., Skelton, B. W., & White, A. H. (1995). Diastereoselective reductions of ß-substituted-¿-keto sulfoximines and a novel palladium(0)-catalysed allylic sulfoximine to allylic sulfinamide rearrangement. Journal of the Chemical Society, Chemical Communications, (4), 445-446. doi:10.1039/C39950000445

Scopus Eid


  • 2-s2.0-0028920762

Web Of Science Accession Number


Start Page


  • 445

End Page


  • 446

Issue


  • 4

Abstract


  • The reduction of β-substituted-γ-keto N-tosyl sulfoximines is highly diastereoselective and the allylic sulfoximines products undergo a facile rearrangement to allylic sulfinamides in the presence of a palladium(0) catalyst.

Publication Date


  • 1995

Citation


  • Pyne, S. G., Dong, Z., Skelton, B. W., & White, A. H. (1995). Diastereoselective reductions of ß-substituted-¿-keto sulfoximines and a novel palladium(0)-catalysed allylic sulfoximine to allylic sulfinamide rearrangement. Journal of the Chemical Society, Chemical Communications, (4), 445-446. doi:10.1039/C39950000445

Scopus Eid


  • 2-s2.0-0028920762

Web Of Science Accession Number


Start Page


  • 445

End Page


  • 446

Issue


  • 4