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Asymmetric intramolecular conjugate addition of amines to chiral vinyl sulphoximides. Total synthesis of (R)-(+)- and (S)-(¿) -Carnegine

Journal Article


Abstract


  • The chiral vinyl sulphoximides (3a) and (3b) upon treatment with base, undergo cyclization to give chiral isoquinolines which were converted into (R)-(+) and (S)-(-)-carnegine. © Royal Society of Chemistry.

Publication Date


  • 1986

Citation


  • Pyne, S. G. (1986). Asymmetric intramolecular conjugate addition of amines to chiral vinyl sulphoximides. Total synthesis of (R)-(+)- and (S)-(¿) -Carnegine. Journal of the Chemical Society - Series Chemical Communications, 1686-1687. doi:10.1039/C39860001686

Scopus Eid


  • 2-s2.0-37049072507

Web Of Science Accession Number


Start Page


  • 1686

End Page


  • 1687

Abstract


  • The chiral vinyl sulphoximides (3a) and (3b) upon treatment with base, undergo cyclization to give chiral isoquinolines which were converted into (R)-(+) and (S)-(-)-carnegine. © Royal Society of Chemistry.

Publication Date


  • 1986

Citation


  • Pyne, S. G. (1986). Asymmetric intramolecular conjugate addition of amines to chiral vinyl sulphoximides. Total synthesis of (R)-(+)- and (S)-(¿) -Carnegine. Journal of the Chemical Society - Series Chemical Communications, 1686-1687. doi:10.1039/C39860001686

Scopus Eid


  • 2-s2.0-37049072507

Web Of Science Accession Number


Start Page


  • 1686

End Page


  • 1687