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Bis(ferrocenyl)porphyrins. Compounds with strong long-range metal-metal coupling

Journal Article


Abstract


  • The condensation of a dipyrromethane with ferrocene aldehyde leads to a single atropisomer of α,α-5,15-bis(ferrocenyl)-2,8,12,18-tetrabutyl-3,7,13,17-tetramethylporphyrin 1; electrochemistry of 1 and Ni-1 reveals two consecutive ferrocene-based one-electron oxidation waves, which are separated by 0.19 and 0.41 V, respectively.

Publication Date


  • 1999

Citation


  • Boyd, P. D. W., Burrell, A. K., Campbell, W. M., Cocks, P. A., Gordon, K. C., Jameson, G. B., . . . Zhao, Z. (1999). Bis(ferrocenyl)porphyrins. Compounds with strong long-range metal-metal coupling. Chemical Communications, (7), 637-638.

Scopus Eid


  • 2-s2.0-0033531614

Start Page


  • 637

End Page


  • 638

Issue


  • 7

Abstract


  • The condensation of a dipyrromethane with ferrocene aldehyde leads to a single atropisomer of α,α-5,15-bis(ferrocenyl)-2,8,12,18-tetrabutyl-3,7,13,17-tetramethylporphyrin 1; electrochemistry of 1 and Ni-1 reveals two consecutive ferrocene-based one-electron oxidation waves, which are separated by 0.19 and 0.41 V, respectively.

Publication Date


  • 1999

Citation


  • Boyd, P. D. W., Burrell, A. K., Campbell, W. M., Cocks, P. A., Gordon, K. C., Jameson, G. B., . . . Zhao, Z. (1999). Bis(ferrocenyl)porphyrins. Compounds with strong long-range metal-metal coupling. Chemical Communications, (7), 637-638.

Scopus Eid


  • 2-s2.0-0033531614

Start Page


  • 637

End Page


  • 638

Issue


  • 7