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Diastereoselective reactions and rearrangements of chiral allylic sulfoximines

Journal Article


Abstract


  • The nucleophilic and electrophilic chemistry of chiral allylic sulfominines and their alkyl sulfoximine counterparts are described including the synthesis of highly functionalised cyclopropanes derivatives. The synthesis of primary and secondary N-tosyl allylic amines via the palladium(0) catalysed rearrangement of allylic sulfoximines to allylic sulfinamides is also described.

Publication Date


  • 1997

Citation


  • Pyne, S. G., Dong, Z., David, D. M., & O'Meara, G. W. (1997). Diastereoselective reactions and rearrangements of chiral allylic sulfoximines. Phosphorus, Sulfur and Silicon and Related Elements, 120-121, 275-289. doi:10.1080/10426509708545524

Scopus Eid


  • 2-s2.0-4244150349

Web Of Science Accession Number


Start Page


  • 275

End Page


  • 289

Volume


  • 120-121

Abstract


  • The nucleophilic and electrophilic chemistry of chiral allylic sulfominines and their alkyl sulfoximine counterparts are described including the synthesis of highly functionalised cyclopropanes derivatives. The synthesis of primary and secondary N-tosyl allylic amines via the palladium(0) catalysed rearrangement of allylic sulfoximines to allylic sulfinamides is also described.

Publication Date


  • 1997

Citation


  • Pyne, S. G., Dong, Z., David, D. M., & O'Meara, G. W. (1997). Diastereoselective reactions and rearrangements of chiral allylic sulfoximines. Phosphorus, Sulfur and Silicon and Related Elements, 120-121, 275-289. doi:10.1080/10426509708545524

Scopus Eid


  • 2-s2.0-4244150349

Web Of Science Accession Number


Start Page


  • 275

End Page


  • 289

Volume


  • 120-121