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Palladium(0) catalysed rearrangements of allylic sulfoximines to allyl sulfinimidic acid esters and optically active N-Cbz protected ¿-amino- enomes

Journal Article


Abstract


  • N-Tosyl allylic sulfoximines undergo rearrangement to allyl sulfinimidic acid esters in the presence of bidentate chiral ligands while N-Cbz allylic sulfoximines give optically active N-Cbz protected γ-amino-enones.

Publication Date


  • 1998

Citation


  • Pyne, S. G., David, D. M., & Dong, Z. (1998). Palladium(0) catalysed rearrangements of allylic sulfoximines to allyl sulfinimidic acid esters and optically active N-Cbz protected ¿-amino- enomes. Tetrahedron Letters, 39(46), 8499-8502. doi:10.1016/S0040-4039(98)01847-4

Scopus Eid


  • 2-s2.0-0032511949

Web Of Science Accession Number


Start Page


  • 8499

End Page


  • 8502

Volume


  • 39

Issue


  • 46

Abstract


  • N-Tosyl allylic sulfoximines undergo rearrangement to allyl sulfinimidic acid esters in the presence of bidentate chiral ligands while N-Cbz allylic sulfoximines give optically active N-Cbz protected γ-amino-enones.

Publication Date


  • 1998

Citation


  • Pyne, S. G., David, D. M., & Dong, Z. (1998). Palladium(0) catalysed rearrangements of allylic sulfoximines to allyl sulfinimidic acid esters and optically active N-Cbz protected ¿-amino- enomes. Tetrahedron Letters, 39(46), 8499-8502. doi:10.1016/S0040-4039(98)01847-4

Scopus Eid


  • 2-s2.0-0032511949

Web Of Science Accession Number


Start Page


  • 8499

End Page


  • 8502

Volume


  • 39

Issue


  • 46