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Alkali-Metal Sulfide as Cathodes toward Safe and High-Capacity Metal (M = Li, Na, K) Sulfur Batteries

Journal Article


Abstract


  • Rechargeable alkali-metal–sulfur (M–S) batteries, because of their high energy density and low cost, have been recognized as one of the most promising next-generation energy storage technologies. Nevertheless, the dissolution of metal polysulfides in organic liquid electrolytes and safety issues related to the metal anodes are greatly hindering the development of the M–S batteries. Alkali-metal sulfides (M2Sx) are emerging as cathode materials, which can pair with various safe nonalkali-metal anodes, such as silicon and tin. As a result, the combined M2Sx cathode-based M–S batteries can achieve high capacity as well as safety, thereby providing a more feasible battery technology for practical applications. In this review, recent progress in developing M2Sx cathode-based M–S batteries is systematically summarized, including the activation methods for M2Sx cathodes, M2Sx cathode optimization, and the improvement of electrolytes and anode materials. Furthermore, perspectives and future research directions of M2Sx cathode-based M–S batteries are proposed.

Publication Date


  • 2020

Citation


  • Yang, H., Zhang, B., Wang, Y. X., Konstantinov, K., Liu, H. K., & Dou, S. X. (2020). Alkali-Metal Sulfide as Cathodes toward Safe and High-Capacity Metal (M = Li, Na, K) Sulfur Batteries. Advanced Energy Materials, 10(37). doi:10.1002/aenm.202001764

Scopus Eid


  • 2-s2.0-85089959416

Volume


  • 10

Issue


  • 37

Abstract


  • Rechargeable alkali-metal–sulfur (M–S) batteries, because of their high energy density and low cost, have been recognized as one of the most promising next-generation energy storage technologies. Nevertheless, the dissolution of metal polysulfides in organic liquid electrolytes and safety issues related to the metal anodes are greatly hindering the development of the M–S batteries. Alkali-metal sulfides (M2Sx) are emerging as cathode materials, which can pair with various safe nonalkali-metal anodes, such as silicon and tin. As a result, the combined M2Sx cathode-based M–S batteries can achieve high capacity as well as safety, thereby providing a more feasible battery technology for practical applications. In this review, recent progress in developing M2Sx cathode-based M–S batteries is systematically summarized, including the activation methods for M2Sx cathodes, M2Sx cathode optimization, and the improvement of electrolytes and anode materials. Furthermore, perspectives and future research directions of M2Sx cathode-based M–S batteries are proposed.

Publication Date


  • 2020

Citation


  • Yang, H., Zhang, B., Wang, Y. X., Konstantinov, K., Liu, H. K., & Dou, S. X. (2020). Alkali-Metal Sulfide as Cathodes toward Safe and High-Capacity Metal (M = Li, Na, K) Sulfur Batteries. Advanced Energy Materials, 10(37). doi:10.1002/aenm.202001764

Scopus Eid


  • 2-s2.0-85089959416

Volume


  • 10

Issue


  • 37