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Pd-Catalyzed Vinylation of Aryl Halides with Inexpensive Organosilicon Reagents Under Mild Conditions.

Journal Article


Abstract


  • Pd-catalyzed Hiyama vinylation reaction of non-activated aryl chlorides and bromides under mild conditions was developed. The use of efficient vinyl donors and electron-rich sterically hindered phosphine ligands was critical for the success of the reaction. The products of this transformation can be used for Am/Cm separation, an important challenge in nuclear fuel reprocessing. The substituent effect on Am/Cm separating selectivity was also achieved, which could contribute to the development of new chromatographic materials for the separation of Am and Cm.

Publication Date


  • 2018

Citation


  • Yang, C. -T., Han, J., Liu, J., Li, Y., Zhang, F., Yu, H. -Z., . . . Wang, X. (2018). Pd-Catalyzed Vinylation of Aryl Halides with Inexpensive Organosilicon Reagents Under Mild Conditions.. Chemistry (Weinheim an der Bergstrasse, Germany), 24(41), 10324-10328. doi:10.1002/chem.201802573

Web Of Science Accession Number


Start Page


  • 10324

End Page


  • 10328

Volume


  • 24

Issue


  • 41

Abstract


  • Pd-catalyzed Hiyama vinylation reaction of non-activated aryl chlorides and bromides under mild conditions was developed. The use of efficient vinyl donors and electron-rich sterically hindered phosphine ligands was critical for the success of the reaction. The products of this transformation can be used for Am/Cm separation, an important challenge in nuclear fuel reprocessing. The substituent effect on Am/Cm separating selectivity was also achieved, which could contribute to the development of new chromatographic materials for the separation of Am and Cm.

Publication Date


  • 2018

Citation


  • Yang, C. -T., Han, J., Liu, J., Li, Y., Zhang, F., Yu, H. -Z., . . . Wang, X. (2018). Pd-Catalyzed Vinylation of Aryl Halides with Inexpensive Organosilicon Reagents Under Mild Conditions.. Chemistry (Weinheim an der Bergstrasse, Germany), 24(41), 10324-10328. doi:10.1002/chem.201802573

Web Of Science Accession Number


Start Page


  • 10324

End Page


  • 10328

Volume


  • 24

Issue


  • 41