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Theoretical study of local structure for Ni2+ ions at tetragonal sites in K2ZnF4:Ni2+ system.

Journal Article


Abstract


  • A theoretical method for studying the local lattice structure of Ni2+ ions in (NiF6)(4-) coordination complex is presented. Using the ligand-field model, the formulas relating the microscopic spin Hamiltonian parameters with the crystal structure parameters are derived. Based on the theoretical formulas, the 45 x 45 complete energy matrices for d8 (d2) configuration ions in a tetragonal ligand-field are constructed. By diagonalizing the complete energy matrices, the local distortion structure parameters (R perpendicular and R || ) of Ni2+ ions in K2ZnF4:Ni2+ system have been investigated. The theoretical results are accorded well with the experimental values. Moreover, to understand the detailed physical and chemical properties of the fluoroperovskite crystals, the theoretical values of the g factor of K2ZnF4:Ni2+ system at 78 and 290 K are reported first.

Publication Date


  • 2008

Citation


  • Wang, S. -J., Kuang, X. -Y., & Lu, C. (2008). Theoretical study of local structure for Ni2+ ions at tetragonal sites in K2ZnF4:Ni2+ system.. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 71(4), 1317-1320. doi:10.1016/j.saa.2008.04.002

Web Of Science Accession Number


Start Page


  • 1317

End Page


  • 1320

Volume


  • 71

Issue


  • 4

Abstract


  • A theoretical method for studying the local lattice structure of Ni2+ ions in (NiF6)(4-) coordination complex is presented. Using the ligand-field model, the formulas relating the microscopic spin Hamiltonian parameters with the crystal structure parameters are derived. Based on the theoretical formulas, the 45 x 45 complete energy matrices for d8 (d2) configuration ions in a tetragonal ligand-field are constructed. By diagonalizing the complete energy matrices, the local distortion structure parameters (R perpendicular and R || ) of Ni2+ ions in K2ZnF4:Ni2+ system have been investigated. The theoretical results are accorded well with the experimental values. Moreover, to understand the detailed physical and chemical properties of the fluoroperovskite crystals, the theoretical values of the g factor of K2ZnF4:Ni2+ system at 78 and 290 K are reported first.

Publication Date


  • 2008

Citation


  • Wang, S. -J., Kuang, X. -Y., & Lu, C. (2008). Theoretical study of local structure for Ni2+ ions at tetragonal sites in K2ZnF4:Ni2+ system.. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 71(4), 1317-1320. doi:10.1016/j.saa.2008.04.002

Web Of Science Accession Number


Start Page


  • 1317

End Page


  • 1320

Volume


  • 71

Issue


  • 4