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Erratum: Corrected Structure of Natural Hyacinthacine C1 via Total Synthesis (Journal of Natural Products (2019) 82: 2 (358¿367) DOI: 10.1021/acs.jnatprod.8b00879)

Journal Article


Abstract


  • Metrics & More. Article Recommendations. Page 365, For the synthesis of (3aR,4R,6R,7R,8S,8aS,8bS)-7,8-Bisbenzyloxy-6-[(benzyloxy)-methyl]-4-methylhexahydro-4H-[1,3,2]dioxathiolo[4,5-a]-pyrrolizine 2,2-dioxide (26), the reagent SOCl2 should be replaced by SO2Cl2. This reagent (SO2Cl2) is correctly shown in the Scheme. The correct text is: (3aR,4R,6R,7R,8S,8aS,8bS)-7,8-Bisbenzyloxy-6-[(benzyloxy)-methyl]-4-methylhexahydro-4H-[1,3,2]dioxathiolo[4,5-a]-pyrrolizine 2,2-dioxide (26). To a solution of the diol 25 (25 mg, 0.0511 mmol) in anhydrous CH2Cl2 (5 mL) under a nitrogen atmosphere was added at 0 °C Et3 N (18 μL, 0.128 mmol), then SO2Cl2 (1.0 M solution in CH2Cl2, 0.0766 μL, 0.0766 mmol) dropwise.

Publication Date


  • 2020

Citation


  • Carroll, A. W., Willis, A. C., Hoshino, M., Kato, A., & Pyne, S. G. (2020). Erratum: Corrected Structure of Natural Hyacinthacine C1 via Total Synthesis (Journal of Natural Products (2019) 82: 2 (358¿367) DOI: 10.1021/acs.jnatprod.8b00879). Journal of Natural Products, 83(5), 1733. doi:10.1021/acs.jnatprod.0c00389

Scopus Eid


  • 2-s2.0-85084312835

Start Page


  • 1733

Volume


  • 83

Issue


  • 5

Abstract


  • Metrics & More. Article Recommendations. Page 365, For the synthesis of (3aR,4R,6R,7R,8S,8aS,8bS)-7,8-Bisbenzyloxy-6-[(benzyloxy)-methyl]-4-methylhexahydro-4H-[1,3,2]dioxathiolo[4,5-a]-pyrrolizine 2,2-dioxide (26), the reagent SOCl2 should be replaced by SO2Cl2. This reagent (SO2Cl2) is correctly shown in the Scheme. The correct text is: (3aR,4R,6R,7R,8S,8aS,8bS)-7,8-Bisbenzyloxy-6-[(benzyloxy)-methyl]-4-methylhexahydro-4H-[1,3,2]dioxathiolo[4,5-a]-pyrrolizine 2,2-dioxide (26). To a solution of the diol 25 (25 mg, 0.0511 mmol) in anhydrous CH2Cl2 (5 mL) under a nitrogen atmosphere was added at 0 °C Et3 N (18 μL, 0.128 mmol), then SO2Cl2 (1.0 M solution in CH2Cl2, 0.0766 μL, 0.0766 mmol) dropwise.

Publication Date


  • 2020

Citation


  • Carroll, A. W., Willis, A. C., Hoshino, M., Kato, A., & Pyne, S. G. (2020). Erratum: Corrected Structure of Natural Hyacinthacine C1 via Total Synthesis (Journal of Natural Products (2019) 82: 2 (358¿367) DOI: 10.1021/acs.jnatprod.8b00879). Journal of Natural Products, 83(5), 1733. doi:10.1021/acs.jnatprod.0c00389

Scopus Eid


  • 2-s2.0-85084312835

Start Page


  • 1733

Volume


  • 83

Issue


  • 5