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Erratum: Total synthesis of natural hyacinthacine C5 and six related hyacinthacine C5 epimers (The Journal of Organic Chemistry (2018) 83:10 (5558-5576) DOI: 10.1021/acs.joc.8b00585)

Journal Article


Abstract


  • In the section: General Method for the Formation of a Cyclic Sulfate, the reagent SOCl2 should be replaced by SO2Cl2. This reagent (SO2Cl2) is correctly shown in the original schemes. The correct text is General Method for the Formation of a Cyclic Sulfate. (3aR,4R,6R,7R,8R,8aS,8bS)-7,8-Bis(benzyloxy)-6-((benzyloxy)methyl)-4-methylhexahydro-4H-[1,3,2]dioxathiolo[4,5-a]-pyrrolizine 2,2-dioxide (48). To a solution of the diol 46 (48 mg, 0.098 mmol) in anhydrous CH2Cl22 (5 mL) under a nitrogen atmosphere was added at 0 °C, Et3N (35 μL, 0.25 mmol), and then SO2Cl2 (12 &mulL, 0.15 mmol) dropwise.

Publication Date


  • 2020

Citation


  • Carroll, A. W., Savaspun, K., Willis, A. C., Hoshino, M., Kato, A., & Pyne, S. G. (2020). Erratum: Total synthesis of natural hyacinthacine C5 and six related hyacinthacine C5 epimers (The Journal of Organic Chemistry (2018) 83:10 (5558-5576) DOI: 10.1021/acs.joc.8b00585). Journal of Organic Chemistry, 85(9), 6242. doi:10.1021/acs.joc.0c00855

Scopus Eid


  • 2-s2.0-85084834700

Start Page


  • 6242

Volume


  • 85

Issue


  • 9

Abstract


  • In the section: General Method for the Formation of a Cyclic Sulfate, the reagent SOCl2 should be replaced by SO2Cl2. This reagent (SO2Cl2) is correctly shown in the original schemes. The correct text is General Method for the Formation of a Cyclic Sulfate. (3aR,4R,6R,7R,8R,8aS,8bS)-7,8-Bis(benzyloxy)-6-((benzyloxy)methyl)-4-methylhexahydro-4H-[1,3,2]dioxathiolo[4,5-a]-pyrrolizine 2,2-dioxide (48). To a solution of the diol 46 (48 mg, 0.098 mmol) in anhydrous CH2Cl22 (5 mL) under a nitrogen atmosphere was added at 0 °C, Et3N (35 μL, 0.25 mmol), and then SO2Cl2 (12 &mulL, 0.15 mmol) dropwise.

Publication Date


  • 2020

Citation


  • Carroll, A. W., Savaspun, K., Willis, A. C., Hoshino, M., Kato, A., & Pyne, S. G. (2020). Erratum: Total synthesis of natural hyacinthacine C5 and six related hyacinthacine C5 epimers (The Journal of Organic Chemistry (2018) 83:10 (5558-5576) DOI: 10.1021/acs.joc.8b00585). Journal of Organic Chemistry, 85(9), 6242. doi:10.1021/acs.joc.0c00855

Scopus Eid


  • 2-s2.0-85084834700

Start Page


  • 6242

Volume


  • 85

Issue


  • 9