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Electrochemically driven actuators from conducting polymers, hydrogels and carbon nanotubes

Conference Paper


Abstract


  • The mechanisms of actuation operating in polymeric actuators are reviewed along with a comparison of actuator performance. Polymer hydrogel actuators show very large dimensional changes, but relatively low response times. The mechanism of actuation involves several processes including electro-osmosis and electrochemical effects. Conducting polymer actuators operate by Faradaic reactions causing oxidation and reduction of the polymer backbone. Associated ion movements produce dimensional changes of typically up to 3%. The maximum stress achieved to date from conducting polymers is not more than 10 MPa. Carbon nanotubes have recently been demonstrated as new actuator materials. The nanotubes undergo useful dimensional changes (∼1%) but have the capacity to respond very rapidly (kHz) and generate giant stresses (600 MPa). The advantages of nanotube actuators stem from their exceptional mechanical properties and the non-Faradaic actuation mechanism.

Publication Date


  • 2001

Citation


  • Spinks, G. M., Wallace, G. G., Lewis, T. W., Fifield, L., Dai, L., & Baughman, R. H. (2001). Electrochemically driven actuators from conducting polymers, hydrogels and carbon nanotubes. In Proceedings of SPIE- The International Society for Optical Engineering Vol. 4234 (pp. 223-231). doi:10.1117/12.424410

Scopus Eid


  • 2-s2.0-0034988454

Start Page


  • 223

End Page


  • 231

Volume


  • 4234

Abstract


  • The mechanisms of actuation operating in polymeric actuators are reviewed along with a comparison of actuator performance. Polymer hydrogel actuators show very large dimensional changes, but relatively low response times. The mechanism of actuation involves several processes including electro-osmosis and electrochemical effects. Conducting polymer actuators operate by Faradaic reactions causing oxidation and reduction of the polymer backbone. Associated ion movements produce dimensional changes of typically up to 3%. The maximum stress achieved to date from conducting polymers is not more than 10 MPa. Carbon nanotubes have recently been demonstrated as new actuator materials. The nanotubes undergo useful dimensional changes (∼1%) but have the capacity to respond very rapidly (kHz) and generate giant stresses (600 MPa). The advantages of nanotube actuators stem from their exceptional mechanical properties and the non-Faradaic actuation mechanism.

Publication Date


  • 2001

Citation


  • Spinks, G. M., Wallace, G. G., Lewis, T. W., Fifield, L., Dai, L., & Baughman, R. H. (2001). Electrochemically driven actuators from conducting polymers, hydrogels and carbon nanotubes. In Proceedings of SPIE- The International Society for Optical Engineering Vol. 4234 (pp. 223-231). doi:10.1117/12.424410

Scopus Eid


  • 2-s2.0-0034988454

Start Page


  • 223

End Page


  • 231

Volume


  • 4234