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Fabrication of symmetric supercapacitors based on MOF-derived nanoporous carbons

Journal Article


Abstract


  • Nanoporous carbon (NPC) materials with high specific surface area have attracted considerable attention for electrochemical energy storage applications. In the present work, we have designed novel symmetric supercapacitors based on NPC by direct carbonization of Zn-based metal-organic frameworks (MOFs) without using an additional precursor. By controlling the reaction conditions in the present study, we synthesized NPC with two different particle sizes. The effects of particle size and mass loadings on supercapacitor performance have been carefully evaluated. Our NPC materials exhibit excellent electrochemical performance with a maximum specific capacitance of 251 F g-1 in 1 M H2SO4 electrolyte. The symmetric supercapacitor studies show that these efficient electrodes have good capacitance, high stability, and good rate capability.

Authors


  •   Salunkhe, Rahul R. (external author)
  •   Kamachi, Yuichiro (external author)
  •   Torad, Nagy L. (external author)
  •   Hwang, Soomin (external author)
  •   Sun, Ziqi
  •   Dou, Shi Xue
  •   Kim, Jung Ho
  •   Yamauchi, Yusuke (external author)

Publication Date


  • 2014

Citation


  • Salunkhe, R. R., Kamachi, Y., Torad, N. L., Hwang, S., Sun, Z., Dou, S. Xue., Kim, J. & Yamauchi, Y. (2014). Fabrication of symmetric supercapacitors based on MOF-derived nanoporous carbons. Journal of Materials Chemistry A, 2 (46), 19848-19854.

Scopus Eid


  • 2-s2.0-84908638623

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/1306

Has Global Citation Frequency


Number Of Pages


  • 6

Start Page


  • 19848

End Page


  • 19854

Volume


  • 2

Issue


  • 46

Place Of Publication


  • United Kingdom

Abstract


  • Nanoporous carbon (NPC) materials with high specific surface area have attracted considerable attention for electrochemical energy storage applications. In the present work, we have designed novel symmetric supercapacitors based on NPC by direct carbonization of Zn-based metal-organic frameworks (MOFs) without using an additional precursor. By controlling the reaction conditions in the present study, we synthesized NPC with two different particle sizes. The effects of particle size and mass loadings on supercapacitor performance have been carefully evaluated. Our NPC materials exhibit excellent electrochemical performance with a maximum specific capacitance of 251 F g-1 in 1 M H2SO4 electrolyte. The symmetric supercapacitor studies show that these efficient electrodes have good capacitance, high stability, and good rate capability.

Authors


  •   Salunkhe, Rahul R. (external author)
  •   Kamachi, Yuichiro (external author)
  •   Torad, Nagy L. (external author)
  •   Hwang, Soomin (external author)
  •   Sun, Ziqi
  •   Dou, Shi Xue
  •   Kim, Jung Ho
  •   Yamauchi, Yusuke (external author)

Publication Date


  • 2014

Citation


  • Salunkhe, R. R., Kamachi, Y., Torad, N. L., Hwang, S., Sun, Z., Dou, S. Xue., Kim, J. & Yamauchi, Y. (2014). Fabrication of symmetric supercapacitors based on MOF-derived nanoporous carbons. Journal of Materials Chemistry A, 2 (46), 19848-19854.

Scopus Eid


  • 2-s2.0-84908638623

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/1306

Has Global Citation Frequency


Number Of Pages


  • 6

Start Page


  • 19848

End Page


  • 19854

Volume


  • 2

Issue


  • 46

Place Of Publication


  • United Kingdom