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Post-synthetic pore-space expansion in a di-tagged metal–organic framework

Journal Article


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Abstract


  • A rarely observed example of post-synthetically increasing pore space, while retaining the chemical functionality of the original metal–organic framework is reported. Conventional solvothermal heating in air was used to effect an efficient post-synthetic rearrangement of a bisallyloxy-tagged zinc metal–organic framework. This leads to the pore-space expanded MOF displaying a higher surface area yet lower affinity for CO2 sorption compared to the original MOF.

UOW Authors


  •   Tshering, Lodey (external author)
  •   Hunter, Sally O. (external author)
  •   Nikolich, Alexandra (external author)
  •   Minato, Erica (external author)
  •   Fitchett, Christopher M. (external author)
  •   D'Alessandro, Deanna (external author)
  •   Richardson, Christopher

Publication Date


  • 2014

Citation


  • Tshering, L., Hunter, S. O., Nikolich, A., Minato, E., Fitchett, C. M., D'Alessandro, D. & Richardson, C. (2014). Post-synthetic pore-space expansion in a di-tagged metal–organic framework. CrystEngComm, 16 (39), 9158-9162.

Scopus Eid


  • 2-s2.0-84907718493

Ro Full-text Url


  • http://ro.uow.edu.au/cgi/viewcontent.cgi?article=3209&context=smhpapers

Ro Metadata Url


  • http://ro.uow.edu.au/smhpapers/2191

Has Global Citation Frequency


Number Of Pages


  • 4

Start Page


  • 9158

End Page


  • 9162

Volume


  • 16

Issue


  • 39

Place Of Publication


  • United Kingdom

Abstract


  • A rarely observed example of post-synthetically increasing pore space, while retaining the chemical functionality of the original metal–organic framework is reported. Conventional solvothermal heating in air was used to effect an efficient post-synthetic rearrangement of a bisallyloxy-tagged zinc metal–organic framework. This leads to the pore-space expanded MOF displaying a higher surface area yet lower affinity for CO2 sorption compared to the original MOF.

UOW Authors


  •   Tshering, Lodey (external author)
  •   Hunter, Sally O. (external author)
  •   Nikolich, Alexandra (external author)
  •   Minato, Erica (external author)
  •   Fitchett, Christopher M. (external author)
  •   D'Alessandro, Deanna (external author)
  •   Richardson, Christopher

Publication Date


  • 2014

Citation


  • Tshering, L., Hunter, S. O., Nikolich, A., Minato, E., Fitchett, C. M., D'Alessandro, D. & Richardson, C. (2014). Post-synthetic pore-space expansion in a di-tagged metal–organic framework. CrystEngComm, 16 (39), 9158-9162.

Scopus Eid


  • 2-s2.0-84907718493

Ro Full-text Url


  • http://ro.uow.edu.au/cgi/viewcontent.cgi?article=3209&context=smhpapers

Ro Metadata Url


  • http://ro.uow.edu.au/smhpapers/2191

Has Global Citation Frequency


Number Of Pages


  • 4

Start Page


  • 9158

End Page


  • 9162

Volume


  • 16

Issue


  • 39

Place Of Publication


  • United Kingdom