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A germanium/single-walled carbon nanotube composite paper as a free-standing anode for lithium-ion batteries

Journal Article


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Abstract


  • Paper-like free-standing germanium (Ge) and single-walled carbon nanotube (SWCNT) composite anodes were synthesized by the vacuum filtration of Ge/SWCNT composites, which were prepared by a facile aqueous-based method. The samples were characterized by X-ray diffraction, field emission scanning electron microscopy, and transmission electron microscopy. Electrochemical measurements demonstrate that the Ge/SWCNT composite paper anode with the weight percentage of 32% Ge delivered a specific discharge capacity of 417 mA h g−1 after 40 cycles at a current density of 25 mA g−1, 117% higher than the pure SWCNT paper anode. The SWCNTs not only function as a flexible mechanical support for strain release, but also provide excellent electrically conducting channels, while the nanosized Ge particles contribute to improving the discharge capacity of the paper anode.

Publication Date


  • 2014

Citation


  • Wang, J., Wang, J., Sun, Z., Gao, X., Zhong, C., Chou, S. & Liu, H. (2014). A germanium/single-walled carbon nanotube composite paper as a free-standing anode for lithium-ion batteries. Journal of Materials Chemistry A, 2 (13), 4613-4618.

Scopus Eid


  • 2-s2.0-84897722938

Ro Full-text Url


  • http://ro.uow.edu.au/cgi/viewcontent.cgi?article=2019&context=aiimpapers

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/1018

Number Of Pages


  • 5

Start Page


  • 4613

End Page


  • 4618

Volume


  • 2

Issue


  • 13

Abstract


  • Paper-like free-standing germanium (Ge) and single-walled carbon nanotube (SWCNT) composite anodes were synthesized by the vacuum filtration of Ge/SWCNT composites, which were prepared by a facile aqueous-based method. The samples were characterized by X-ray diffraction, field emission scanning electron microscopy, and transmission electron microscopy. Electrochemical measurements demonstrate that the Ge/SWCNT composite paper anode with the weight percentage of 32% Ge delivered a specific discharge capacity of 417 mA h g−1 after 40 cycles at a current density of 25 mA g−1, 117% higher than the pure SWCNT paper anode. The SWCNTs not only function as a flexible mechanical support for strain release, but also provide excellent electrically conducting channels, while the nanosized Ge particles contribute to improving the discharge capacity of the paper anode.

Publication Date


  • 2014

Citation


  • Wang, J., Wang, J., Sun, Z., Gao, X., Zhong, C., Chou, S. & Liu, H. (2014). A germanium/single-walled carbon nanotube composite paper as a free-standing anode for lithium-ion batteries. Journal of Materials Chemistry A, 2 (13), 4613-4618.

Scopus Eid


  • 2-s2.0-84897722938

Ro Full-text Url


  • http://ro.uow.edu.au/cgi/viewcontent.cgi?article=2019&context=aiimpapers

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/1018

Number Of Pages


  • 5

Start Page


  • 4613

End Page


  • 4618

Volume


  • 2

Issue


  • 13