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Manganese-based layered coordination polymer: Synthesis, structural characterization, magnetic property, and electrochemical performance in lithium-ion batteries

Journal Article


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Abstract


  • Manganese-based layered coordination polymer ([Mn(tfbdc)(4,4′-bpy) (H2O)2], Mn-LCP) with microporous structure was synthesized by reaction of 2,3,5,6-tetrafluoroterephthalatic acid(H 2tfbdc) and 4,4′-bipyridine(4,4′-bpy) with manganese(II) acetate tetrahydrate in water solution. Mn-LCP was characterized by elemental analysis, IR spectra, thermogravimetric analysis, X-ray single-crystal structure analysis, and powder X-ray diffraction. Magnetic susceptibility data from 300 to 1.8K show that there is a weak antiferromagnetic exchange between Mn(II) ions in Mn-LCP. As anode material, the Mn-LCP electrode exhibits an irreversible high capacity in the first discharge process and a reversible lithium storage capacity of up to about 390 mA h/g from the fourth cycle. It might provide a new method for finding new electrode materials in lithium-ion batteries © 2013 American Chemical Society.

Authors


  •   Liu, Qi (external author)
  •   Yu, Lili (external author)
  •   Wang, Ying (external author)
  •   Ji, Y (external author)
  •   Horvat, Josip
  •   Cheng, M (external author)
  •   Jia, X (external author)
  •   Wang, Guoxiu

Publication Date


  • 2013

Citation


  • Liu, Q., Yu, L., Wang, Y., Ji, Y., Horvat, J., Cheng, M., Jia, X. & Wang, G. (2013). Manganese-based layered coordination polymer: Synthesis, structural characterization, magnetic property, and electrochemical performance in lithium-ion batteries. Inorganic Chemistry: including bioinorganic chemistry, 52 (6), 2817-2822.

Scopus Eid


  • 2-s2.0-84875157862

Ro Full-text Url


  • http://ro.uow.edu.au/cgi/viewcontent.cgi?article=1614&context=aiimpapers

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/613

Number Of Pages


  • 5

Start Page


  • 2817

End Page


  • 2822

Volume


  • 52

Issue


  • 6

Abstract


  • Manganese-based layered coordination polymer ([Mn(tfbdc)(4,4′-bpy) (H2O)2], Mn-LCP) with microporous structure was synthesized by reaction of 2,3,5,6-tetrafluoroterephthalatic acid(H 2tfbdc) and 4,4′-bipyridine(4,4′-bpy) with manganese(II) acetate tetrahydrate in water solution. Mn-LCP was characterized by elemental analysis, IR spectra, thermogravimetric analysis, X-ray single-crystal structure analysis, and powder X-ray diffraction. Magnetic susceptibility data from 300 to 1.8K show that there is a weak antiferromagnetic exchange between Mn(II) ions in Mn-LCP. As anode material, the Mn-LCP electrode exhibits an irreversible high capacity in the first discharge process and a reversible lithium storage capacity of up to about 390 mA h/g from the fourth cycle. It might provide a new method for finding new electrode materials in lithium-ion batteries © 2013 American Chemical Society.

Authors


  •   Liu, Qi (external author)
  •   Yu, Lili (external author)
  •   Wang, Ying (external author)
  •   Ji, Y (external author)
  •   Horvat, Josip
  •   Cheng, M (external author)
  •   Jia, X (external author)
  •   Wang, Guoxiu

Publication Date


  • 2013

Citation


  • Liu, Q., Yu, L., Wang, Y., Ji, Y., Horvat, J., Cheng, M., Jia, X. & Wang, G. (2013). Manganese-based layered coordination polymer: Synthesis, structural characterization, magnetic property, and electrochemical performance in lithium-ion batteries. Inorganic Chemistry: including bioinorganic chemistry, 52 (6), 2817-2822.

Scopus Eid


  • 2-s2.0-84875157862

Ro Full-text Url


  • http://ro.uow.edu.au/cgi/viewcontent.cgi?article=1614&context=aiimpapers

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/613

Number Of Pages


  • 5

Start Page


  • 2817

End Page


  • 2822

Volume


  • 52

Issue


  • 6