Skip to main content

A reagentless thermal post-synthetic rearrangement of an allyloxy-tagged metal-organic framework

Journal Article


Download full-text (Open Access)

Abstract


  • Direct heating of a metal–organic framework provides a simple, controllable way of effecting a covalent post-synthetic modification. Herein we report that an allyloxy-tagged zinc metal–organic framework undergoes a thermally-promoted aromatic Claisen rearrangement through which the framework connectivity and porosity are maintained.

Authors


  •   Burrows, Andrew D. (external author)
  •   Hunter, Sally O. (external author)
  •   Mahon, Mary F. (external author)
  •   Richardson, Christopher

Publication Date


  • 2013

Citation


  • Burrows, A. D., Hunter, S. O., Mahon, M. F. & Richardson, C. (2013). A reagentless thermal post-synthetic rearrangement of an allyloxy-tagged metal-organic framework. Chemical Communications, 49 (10), 990-992.

Scopus Eid


  • 2-s2.0-84872074662

Ro Full-text Url


  • http://ro.uow.edu.au/cgi/viewcontent.cgi?article=8114&context=scipapers

Ro Metadata Url


  • http://ro.uow.edu.au/scipapers/4771

Has Global Citation Frequency


Number Of Pages


  • 2

Start Page


  • 990

End Page


  • 992

Volume


  • 49

Issue


  • 10

Place Of Publication


  • United Kingdom

Abstract


  • Direct heating of a metal–organic framework provides a simple, controllable way of effecting a covalent post-synthetic modification. Herein we report that an allyloxy-tagged zinc metal–organic framework undergoes a thermally-promoted aromatic Claisen rearrangement through which the framework connectivity and porosity are maintained.

Authors


  •   Burrows, Andrew D. (external author)
  •   Hunter, Sally O. (external author)
  •   Mahon, Mary F. (external author)
  •   Richardson, Christopher

Publication Date


  • 2013

Citation


  • Burrows, A. D., Hunter, S. O., Mahon, M. F. & Richardson, C. (2013). A reagentless thermal post-synthetic rearrangement of an allyloxy-tagged metal-organic framework. Chemical Communications, 49 (10), 990-992.

Scopus Eid


  • 2-s2.0-84872074662

Ro Full-text Url


  • http://ro.uow.edu.au/cgi/viewcontent.cgi?article=8114&context=scipapers

Ro Metadata Url


  • http://ro.uow.edu.au/scipapers/4771

Has Global Citation Frequency


Number Of Pages


  • 2

Start Page


  • 990

End Page


  • 992

Volume


  • 49

Issue


  • 10

Place Of Publication


  • United Kingdom