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Technical Note: Latitude-time variations of atmospheric column-average dry air mole fractions of CO2, CH4 and N2O

Journal Article


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Abstract


  • We present a comparison of an atmospheric general circulation model (AGCM)-based chemistry-transport model (ACTM) simulation with total column measurements of CO2, CH4 and N2O from the Total Carbon Column Observing Network (TCCON). The model is able to capture observed trends, seasonal cycles and inter hemispheric gradients at most sampled locations for all three species. The model-observation agreements are best for CO2, because the simulation uses fossil fuel inventories and an inverse model estimate of non-fossil fuel fluxes. The ACTM captures much of the observed seasonal variability in CO2 and N2O total columns (similar to 81% variance, R > 0.9 between ACTM and TCCON for 19 out of 22 cases). These results suggest that the transport processes in troposphere and stratosphere are well represented in ACTM. Thus the poor correlation between simulated and observed CH4 total columns, particularly at tropical and extra-tropical sites, have been attributed to the uncertainties in surface emissions and loss by hydroxyl radicals. While the upward-looking total column measurements of CO2 contains surface flux signals at various spatial and temporal scales, the N2O measurements are strongly affected by the concentration variations in the upper troposphere and stratosphere.

UOW Authors


  •   Saito, R (external author)
  •   Patra, Prabir K. (external author)
  •   Deutscher, Nicholas
  •   Wunch, Debra (external author)
  •   Ishijima, K (external author)
  •   Sherlock, Vanessa (external author)
  •   Blumenstock, Thomas (external author)
  •   Dohe, Susanne (external author)
  •   Griffith, David
  •   Hase, Frank (external author)
  •   Heikkinen, Pauli (external author)
  •   Kyro, Esko (external author)
  •   Macatangay, Ronald (external author)
  •   Mendonca, J (external author)
  •   Messerschmidt, Janina (external author)
  •   Morino, Isamu (external author)
  •   Notholt, Justus (external author)
  •   Rettinger, Markus (external author)
  •   Strong, Kimberly (external author)
  •   Sussmann, Ralf (external author)
  •   Warneke, Thorsten (external author)

Publication Date


  • 2012

Citation


  • Saito, R., Patra, P. K., Deutscher, N., Wunch, D., Ishijima, K., Sherlock, V., Blumenstock, T., Dohe, S., Griffith, D., Hase, F., Heikkinen, P., Kyro, E., Macatangay, R., Mendonca, J., Messerschmidt, J., Morino, I., Notholt, J., Rettinger, M., Strong, K., Sussmann, R. & Warneke, T. (2012). Technical Note: Latitude-time variations of atmospheric column-average dry air mole fractions of CO2, CH4 and N2O. Atmospheric Chemistry and Physics, 12 (16), 7767-7777.

Scopus Eid


  • 2-s2.0-84869065664

Ro Full-text Url


  • http://ro.uow.edu.au/cgi/viewcontent.cgi?article=7873&context=scipapers

Ro Metadata Url


  • http://ro.uow.edu.au/scipapers/4531

Has Global Citation Frequency


Number Of Pages


  • 10

Start Page


  • 7767

End Page


  • 7777

Volume


  • 12

Issue


  • 16

Place Of Publication


  • Germany

Abstract


  • We present a comparison of an atmospheric general circulation model (AGCM)-based chemistry-transport model (ACTM) simulation with total column measurements of CO2, CH4 and N2O from the Total Carbon Column Observing Network (TCCON). The model is able to capture observed trends, seasonal cycles and inter hemispheric gradients at most sampled locations for all three species. The model-observation agreements are best for CO2, because the simulation uses fossil fuel inventories and an inverse model estimate of non-fossil fuel fluxes. The ACTM captures much of the observed seasonal variability in CO2 and N2O total columns (similar to 81% variance, R > 0.9 between ACTM and TCCON for 19 out of 22 cases). These results suggest that the transport processes in troposphere and stratosphere are well represented in ACTM. Thus the poor correlation between simulated and observed CH4 total columns, particularly at tropical and extra-tropical sites, have been attributed to the uncertainties in surface emissions and loss by hydroxyl radicals. While the upward-looking total column measurements of CO2 contains surface flux signals at various spatial and temporal scales, the N2O measurements are strongly affected by the concentration variations in the upper troposphere and stratosphere.

UOW Authors


  •   Saito, R (external author)
  •   Patra, Prabir K. (external author)
  •   Deutscher, Nicholas
  •   Wunch, Debra (external author)
  •   Ishijima, K (external author)
  •   Sherlock, Vanessa (external author)
  •   Blumenstock, Thomas (external author)
  •   Dohe, Susanne (external author)
  •   Griffith, David
  •   Hase, Frank (external author)
  •   Heikkinen, Pauli (external author)
  •   Kyro, Esko (external author)
  •   Macatangay, Ronald (external author)
  •   Mendonca, J (external author)
  •   Messerschmidt, Janina (external author)
  •   Morino, Isamu (external author)
  •   Notholt, Justus (external author)
  •   Rettinger, Markus (external author)
  •   Strong, Kimberly (external author)
  •   Sussmann, Ralf (external author)
  •   Warneke, Thorsten (external author)

Publication Date


  • 2012

Citation


  • Saito, R., Patra, P. K., Deutscher, N., Wunch, D., Ishijima, K., Sherlock, V., Blumenstock, T., Dohe, S., Griffith, D., Hase, F., Heikkinen, P., Kyro, E., Macatangay, R., Mendonca, J., Messerschmidt, J., Morino, I., Notholt, J., Rettinger, M., Strong, K., Sussmann, R. & Warneke, T. (2012). Technical Note: Latitude-time variations of atmospheric column-average dry air mole fractions of CO2, CH4 and N2O. Atmospheric Chemistry and Physics, 12 (16), 7767-7777.

Scopus Eid


  • 2-s2.0-84869065664

Ro Full-text Url


  • http://ro.uow.edu.au/cgi/viewcontent.cgi?article=7873&context=scipapers

Ro Metadata Url


  • http://ro.uow.edu.au/scipapers/4531

Has Global Citation Frequency


Number Of Pages


  • 10

Start Page


  • 7767

End Page


  • 7777

Volume


  • 12

Issue


  • 16

Place Of Publication


  • Germany