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Facile synthesis of a interleaved expanded graphite-embedded sulphur nanocomposite as cathode of Li-S batteries with excellent lithium storage performance

Journal Article


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Abstract


  • This paper reports the facile synthesis of a unique interleaved expanded graphite-embedded sulphur nanocomposite (S-EG) by melt-diffusion strategy. The SEM images of the S-EG materials indicate the nanocomposites consist of nanosheets with a layer-by-layer structure. Electrochemical tests reveal that the nanocomposite with a sulphur content of 60% (0.6S-EG) can deliver the highest discharge capacity of 1210.4 mAh g−1 at a charge–discharge rate of 280 mA g−1 in the first cycle, the discharge capacity of the 0.6S-EG remains as high as 957.9 mAh g−1 after 50 cycles of charge–discharge. Furthermore, at a much higher charge–discharge rate of 28 A g−1, the 0.6S-EG cathode can still deliver a high reversible capacity of 337.5 mAh g−1. The high sulphur utilization, excellent rate capability and reduced over-discharge phenomenon of the 0.6S-EG material are exclusively attributed to the particular microstructure and composition of the cathode.

Authors


  •   Wang, Yunxiao
  •   Huang, Ling (external author)
  •   Sun, Li-Chao (external author)
  •   Xie, Su-Yuan (external author)
  •   Xu, Gui-Liang (external author)
  •   Chen, Shu-Ru (external author)
  •   Xu, Yue (external author)
  •   Li, Jun-Tiao (external author)
  •   Chou, Shulei
  •   Dou, Shi Xue
  •   Sun, Shi-Gang (external author)

Publication Date


  • 2012

Citation


  • Wang, Y., Huang, L., Sun, L., Xie, S., Xu, G., Chen, S., Xu, Y., Li, J., Chou, S., Dou, S. & Sun, S. (2012). Facile synthesis of a interleaved expanded graphite-embedded sulphur nanocomposite as cathode of Li-S batteries with excellent lithium storage performance. Journal of Materials Chemistry, 22 (11), 4744-4750.

Scopus Eid


  • 2-s2.0-84863124868

Ro Full-text Url


  • http://ro.uow.edu.au/cgi/viewcontent.cgi?article=8159&context=engpapers

Ro Metadata Url


  • http://ro.uow.edu.au/engpapers/5227

Number Of Pages


  • 6

Start Page


  • 4744

End Page


  • 4750

Volume


  • 22

Issue


  • 11

Abstract


  • This paper reports the facile synthesis of a unique interleaved expanded graphite-embedded sulphur nanocomposite (S-EG) by melt-diffusion strategy. The SEM images of the S-EG materials indicate the nanocomposites consist of nanosheets with a layer-by-layer structure. Electrochemical tests reveal that the nanocomposite with a sulphur content of 60% (0.6S-EG) can deliver the highest discharge capacity of 1210.4 mAh g−1 at a charge–discharge rate of 280 mA g−1 in the first cycle, the discharge capacity of the 0.6S-EG remains as high as 957.9 mAh g−1 after 50 cycles of charge–discharge. Furthermore, at a much higher charge–discharge rate of 28 A g−1, the 0.6S-EG cathode can still deliver a high reversible capacity of 337.5 mAh g−1. The high sulphur utilization, excellent rate capability and reduced over-discharge phenomenon of the 0.6S-EG material are exclusively attributed to the particular microstructure and composition of the cathode.

Authors


  •   Wang, Yunxiao
  •   Huang, Ling (external author)
  •   Sun, Li-Chao (external author)
  •   Xie, Su-Yuan (external author)
  •   Xu, Gui-Liang (external author)
  •   Chen, Shu-Ru (external author)
  •   Xu, Yue (external author)
  •   Li, Jun-Tiao (external author)
  •   Chou, Shulei
  •   Dou, Shi Xue
  •   Sun, Shi-Gang (external author)

Publication Date


  • 2012

Citation


  • Wang, Y., Huang, L., Sun, L., Xie, S., Xu, G., Chen, S., Xu, Y., Li, J., Chou, S., Dou, S. & Sun, S. (2012). Facile synthesis of a interleaved expanded graphite-embedded sulphur nanocomposite as cathode of Li-S batteries with excellent lithium storage performance. Journal of Materials Chemistry, 22 (11), 4744-4750.

Scopus Eid


  • 2-s2.0-84863124868

Ro Full-text Url


  • http://ro.uow.edu.au/cgi/viewcontent.cgi?article=8159&context=engpapers

Ro Metadata Url


  • http://ro.uow.edu.au/engpapers/5227

Number Of Pages


  • 6

Start Page


  • 4744

End Page


  • 4750

Volume


  • 22

Issue


  • 11