LiFePO4–Fe2P–C composite cathode: An environmentally friendly promising electrode material for lithium-ion battery

In this investigation, the synthesis strategy is involved the creation of LiFePO4–Fe2P–C composites with

a porous conductive architecture, which includes distinct regions or clusters containing antiferromagnetic

LiFePO4 in close proximity to ferromagnetic Fe2P. The microstructure is achieved by using a simple

ultra-fast solvent assisted manual grinding method, combined with solid state reaction, which can replace

the time-consuming high energy ball milling method. The crystalline structure, morphology, and electrochemical

characterization of the synthesised product are investigated systematically. The electrochemical

performance is outstanding, especially the high C rate. The composite cathode is found to display specific

capacity of 167 mAh g−1 at 0.2 C and 146 mAh g−1 at 5 C after 100 cycles, respectively. At the high

current density of 1700 mA g−1 (10 C rate), it exhibits long-term cycling stability, retaining around 96%

(131 mAh g−1) of its original discharge capacity beyond 1000 cycles, which can meet the requirements of

a lithium-ion battery for large-scale power applications. The obtained results have demonstrated that the

fabrication of samples with strong and extensive antiferromagnetic and ferromagnetic interface coupling

of LiFePO4/Fe2P provides a versatile strategy toward improving the electrochemical properties of LiFePO4

materials and also opens up a new window for material scientists to further study the new exchange bias

phenomenon and its ability to enhance the electrochemical performance of lithium-ion battery electrode.