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SnO(2)-Graphene composite synthesized via an ultrafast and environmentally friendly microwave autoclave method and its use as a superior anode for lithium-ion batteries

Journal Article


Abstract


  • "SnO(2)-graphene composites have been synthesized by an ultrafast and environmentally friendly microwave autoclave method. From field emission scanning electron microscopy and transmission electron microscopy, it can be determined that the SnO(2) nanoparticles, around 4-S nm in diameter, are uniformly sandwiched between graphene nanosheets containing only a few layers. The successful synthesis demonstrates that in situ loading of SnO(2) nanoparticles can be an effective way to prevent graphene nanosheets from being restacked during the reduction. The Li-cycling properties of the materials have been evaluated by galvanostatic discharge-charge cycling and impedance spectroscopy. Results show that the SnO(2)-graphene composite with a graphene content of 33.3 wt % exhibits a very stable capacity of about 590 mAh g(-1) without noticeable fading for up to 200 cycles."

Publication Date


  • 2011

Citation


  • Zhong, C., Wang, J., Chen, Z. & Liu, H. K. (2011). SnO(2)-Graphene composite synthesized via an ultrafast and environmentally friendly microwave autoclave method and its use as a superior anode for lithium-ion batteries. The Journal of Physical Chemistry Part C: Nanomaterials and Interfaces, 115 (50), 25115-25120.

Scopus Eid


  • 2-s2.0-84863116637

Ro Metadata Url


  • http://ro.uow.edu.au/engpapers/3162

Number Of Pages


  • 5

Start Page


  • 25115

End Page


  • 25120

Volume


  • 115

Issue


  • 50

Abstract


  • "SnO(2)-graphene composites have been synthesized by an ultrafast and environmentally friendly microwave autoclave method. From field emission scanning electron microscopy and transmission electron microscopy, it can be determined that the SnO(2) nanoparticles, around 4-S nm in diameter, are uniformly sandwiched between graphene nanosheets containing only a few layers. The successful synthesis demonstrates that in situ loading of SnO(2) nanoparticles can be an effective way to prevent graphene nanosheets from being restacked during the reduction. The Li-cycling properties of the materials have been evaluated by galvanostatic discharge-charge cycling and impedance spectroscopy. Results show that the SnO(2)-graphene composite with a graphene content of 33.3 wt % exhibits a very stable capacity of about 590 mAh g(-1) without noticeable fading for up to 200 cycles."

Publication Date


  • 2011

Citation


  • Zhong, C., Wang, J., Chen, Z. & Liu, H. K. (2011). SnO(2)-Graphene composite synthesized via an ultrafast and environmentally friendly microwave autoclave method and its use as a superior anode for lithium-ion batteries. The Journal of Physical Chemistry Part C: Nanomaterials and Interfaces, 115 (50), 25115-25120.

Scopus Eid


  • 2-s2.0-84863116637

Ro Metadata Url


  • http://ro.uow.edu.au/engpapers/3162

Number Of Pages


  • 5

Start Page


  • 25115

End Page


  • 25120

Volume


  • 115

Issue


  • 50