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The first metal complexes of 3,3′-bi-1,2,4-oxadiazole: a curiously ignored ligand

Journal Article


Abstract


  • The crystal structure of 3,3′-bi-1,2,4-oxadiazole (1) reveals a planar centrosymmetric structure for this molecule in the solid state. It forms a mononuclear complex (3) with palladium(II) chloride, which is shown by X-ray crystallography to contain the ligand chelated through the two N4 nitrogens. The X-ray structure of the complex (5) with silver(I) nitrate shows a one-dimensional coordination polymer in which the ligand acts in a bridging mode, again with coordination through the N4 nitrogen atoms. © 2007 Elsevier B.V. All rights reserved.

Publication Date


  • 2007

Citation


  • Richardson, C. & Steel, P. J. (2007). The first metal complexes of 3,3′-bi-1,2,4-oxadiazole: a curiously ignored ligand. Inorganic Chemistry Communications, 10 (8), 884-887.

Scopus Eid


  • 2-s2.0-34447556819

Ro Metadata Url


  • http://ro.uow.edu.au/scipapers/4898

Number Of Pages


  • 3

Start Page


  • 884

End Page


  • 887

Volume


  • 10

Issue


  • 8

Abstract


  • The crystal structure of 3,3′-bi-1,2,4-oxadiazole (1) reveals a planar centrosymmetric structure for this molecule in the solid state. It forms a mononuclear complex (3) with palladium(II) chloride, which is shown by X-ray crystallography to contain the ligand chelated through the two N4 nitrogens. The X-ray structure of the complex (5) with silver(I) nitrate shows a one-dimensional coordination polymer in which the ligand acts in a bridging mode, again with coordination through the N4 nitrogen atoms. © 2007 Elsevier B.V. All rights reserved.

Publication Date


  • 2007

Citation


  • Richardson, C. & Steel, P. J. (2007). The first metal complexes of 3,3′-bi-1,2,4-oxadiazole: a curiously ignored ligand. Inorganic Chemistry Communications, 10 (8), 884-887.

Scopus Eid


  • 2-s2.0-34447556819

Ro Metadata Url


  • http://ro.uow.edu.au/scipapers/4898

Number Of Pages


  • 3

Start Page


  • 884

End Page


  • 887

Volume


  • 10

Issue


  • 8