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Selective incorporation of functional dicarboxylates into zinc metal-organic frameworks

Journal Article


Abstract


  • Zinc(ii) nitrate reacts with different ratios of 1,4-benzenedicarboxylic acid (H2bdc) and 2-halo-1,4-benzenedicarboxylic acid (H 2bdc-X, X = Br or I) to give [Zn4O(bdc) 3-x(bdc-X)x], in which preferential incorporation of bdc is observed. The selective incorporation is related to crystal growth rates, and the proportion of incorporated bdc-X rises with increasing reaction time. © 2011 The Royal Society of Chemistry.

    Language of original document

Authors


  •   Burrows, Andrew D. (external author)
  •   Fisher, L C. (external author)
  •   Richardson, Christopher
  •   Rigby, S P. (external author)

Publication Date


  • 2011

Citation


  • Burrows, A. D., Fisher, L. C., Richardson, C. & Rigby, S. P. (2011). Selective incorporation of functional dicarboxylates into zinc metal-organic frameworks. Chemical Communications, 47 (12), 3380-3382.

Scopus Eid


  • 2-s2.0-79952386395

Ro Metadata Url


  • http://ro.uow.edu.au/scipapers/3592

Has Global Citation Frequency


Number Of Pages


  • 2

Start Page


  • 3380

End Page


  • 3382

Volume


  • 47

Issue


  • 12

Abstract


  • Zinc(ii) nitrate reacts with different ratios of 1,4-benzenedicarboxylic acid (H2bdc) and 2-halo-1,4-benzenedicarboxylic acid (H 2bdc-X, X = Br or I) to give [Zn4O(bdc) 3-x(bdc-X)x], in which preferential incorporation of bdc is observed. The selective incorporation is related to crystal growth rates, and the proportion of incorporated bdc-X rises with increasing reaction time. © 2011 The Royal Society of Chemistry.

    Language of original document

Authors


  •   Burrows, Andrew D. (external author)
  •   Fisher, L C. (external author)
  •   Richardson, Christopher
  •   Rigby, S P. (external author)

Publication Date


  • 2011

Citation


  • Burrows, A. D., Fisher, L. C., Richardson, C. & Rigby, S. P. (2011). Selective incorporation of functional dicarboxylates into zinc metal-organic frameworks. Chemical Communications, 47 (12), 3380-3382.

Scopus Eid


  • 2-s2.0-79952386395

Ro Metadata Url


  • http://ro.uow.edu.au/scipapers/3592

Has Global Citation Frequency


Number Of Pages


  • 2

Start Page


  • 3380

End Page


  • 3382

Volume


  • 47

Issue


  • 12