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Dipyridyl beta-diketonate complexes: versatile polydentate metalloligands for metal-organic frameworks and hydrogen-bonded networks

Journal Article


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Abstract


  • The Group 13 metal complexes [M(L-2)(3)], where M is Al or Ga and L-2 is 1,3-di(4-pyridyl)-1,3-propanedionato, are hexatopic metalloligands that have been used to prepare mixed-metalorganic frameworks containing interpenetrated primitive cubic networks. In contrast, the europium complex [Eu(HL2)(3)-(H2L2)]Cl-4 center dot EtOH forms a hydrogen-bonded network following partial protonation of the pyridyl groups.

Authors


  •   Burrows, Andrew D. (external author)
  •   Frost, Christopher (external author)
  •   Mahon, Mary F. (external author)
  •   Raithby, Paul R. (external author)
  •   Renouf, Catherine (external author)
  •   Richardson, Christopher
  •   Stevenson, Anna J. (external author)

Publication Date


  • 2010

Citation


  • Burrows, A. D., Frost, C., Mahon, M. F., Raithby, P. R., Renouf, C., Richardson, C. & Stevenson, A. (2010). Dipyridyl beta-diketonate complexes: versatile polydentate metalloligands for metal-organic frameworks and hydrogen-bonded networks. Chemical Communications, 46 (28), 5067-5069.

Scopus Eid


  • 2-s2.0-77954586771

Ro Full-text Url


  • http://ro.uow.edu.au/cgi/viewcontent.cgi?article=1461&context=scipapers

Ro Metadata Url


  • http://ro.uow.edu.au/scipapers/423

Has Global Citation Frequency


Number Of Pages


  • 2

Start Page


  • 5067

End Page


  • 5069

Volume


  • 46

Issue


  • 28

Abstract


  • The Group 13 metal complexes [M(L-2)(3)], where M is Al or Ga and L-2 is 1,3-di(4-pyridyl)-1,3-propanedionato, are hexatopic metalloligands that have been used to prepare mixed-metalorganic frameworks containing interpenetrated primitive cubic networks. In contrast, the europium complex [Eu(HL2)(3)-(H2L2)]Cl-4 center dot EtOH forms a hydrogen-bonded network following partial protonation of the pyridyl groups.

Authors


  •   Burrows, Andrew D. (external author)
  •   Frost, Christopher (external author)
  •   Mahon, Mary F. (external author)
  •   Raithby, Paul R. (external author)
  •   Renouf, Catherine (external author)
  •   Richardson, Christopher
  •   Stevenson, Anna J. (external author)

Publication Date


  • 2010

Citation


  • Burrows, A. D., Frost, C., Mahon, M. F., Raithby, P. R., Renouf, C., Richardson, C. & Stevenson, A. (2010). Dipyridyl beta-diketonate complexes: versatile polydentate metalloligands for metal-organic frameworks and hydrogen-bonded networks. Chemical Communications, 46 (28), 5067-5069.

Scopus Eid


  • 2-s2.0-77954586771

Ro Full-text Url


  • http://ro.uow.edu.au/cgi/viewcontent.cgi?article=1461&context=scipapers

Ro Metadata Url


  • http://ro.uow.edu.au/scipapers/423

Has Global Citation Frequency


Number Of Pages


  • 2

Start Page


  • 5067

End Page


  • 5069

Volume


  • 46

Issue


  • 28