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Production and isolation of ligated metal(IV)-oxo ions by tandem mass spectrometry

Journal Article


Abstract


  • High valent metal(IV)-oxo species, [M(=O)(Melm)(n)(OAc)](+) (M = Mn-Ni, MeIm = 1-methylimidazole, n = 1-2), which are relevant to biology and oxidative catalysis, were produced and isolated in gas-phase reactions of the metal(II) precursor ions [M(MeIm)(n)(OAc)](+) (M = Mn-Zn, n = 1-3) with ozone. The precursor ions [M(MeIm)(OAc)](+) and [M(MeIm)(2)(OAc)](+) were generated via collision-induced dissociation of the corresponding [M(MeIm)(3)(OAc)](+) ion. The dependence of ozone reactivity on metal and coordination number is discussed. Copyright (C) 2010 John Wiley & Sons, Ltd.

UOW Authors


  •   Taylor, Ivan (external author)
  •   Colbran, Stephen B. (external author)
  •   Willett, Gary (external author)
  •   Blanksby, Stephen J. (external author)

Publication Date


  • 2010

Citation


  • Taylor, I., Blanksby, S. J., Colbran, S. B. & Willett, G. (2010). Production and isolation of ligated metal(IV)-oxo ions by tandem mass spectrometry. Rapid Communications in Mass Spectrometry, 24 (8), 1142-1146.

Scopus Eid


  • 2-s2.0-77950986153

Ro Metadata Url


  • http://ro.uow.edu.au/scipapers/5105

Has Global Citation Frequency


Number Of Pages


  • 4

Start Page


  • 1142

End Page


  • 1146

Volume


  • 24

Issue


  • 8

Abstract


  • High valent metal(IV)-oxo species, [M(=O)(Melm)(n)(OAc)](+) (M = Mn-Ni, MeIm = 1-methylimidazole, n = 1-2), which are relevant to biology and oxidative catalysis, were produced and isolated in gas-phase reactions of the metal(II) precursor ions [M(MeIm)(n)(OAc)](+) (M = Mn-Zn, n = 1-3) with ozone. The precursor ions [M(MeIm)(OAc)](+) and [M(MeIm)(2)(OAc)](+) were generated via collision-induced dissociation of the corresponding [M(MeIm)(3)(OAc)](+) ion. The dependence of ozone reactivity on metal and coordination number is discussed. Copyright (C) 2010 John Wiley & Sons, Ltd.

UOW Authors


  •   Taylor, Ivan (external author)
  •   Colbran, Stephen B. (external author)
  •   Willett, Gary (external author)
  •   Blanksby, Stephen J. (external author)

Publication Date


  • 2010

Citation


  • Taylor, I., Blanksby, S. J., Colbran, S. B. & Willett, G. (2010). Production and isolation of ligated metal(IV)-oxo ions by tandem mass spectrometry. Rapid Communications in Mass Spectrometry, 24 (8), 1142-1146.

Scopus Eid


  • 2-s2.0-77950986153

Ro Metadata Url


  • http://ro.uow.edu.au/scipapers/5105

Has Global Citation Frequency


Number Of Pages


  • 4

Start Page


  • 1142

End Page


  • 1146

Volume


  • 24

Issue


  • 8