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Preparation of alpha-Fe2O3 submicro-flowers by a hydrothermal approach and their electrochemical performance in lithium-ion batteries

Journal Article


Abstract


  • Uniform alpha-Fe2O3 submicron-sized flowers have been synthesized by a simple hydrothermal process conducted at 160 degrees C for 024 h. The crystalline structure and morphology of the as-synthesized powder have been characterized by using X-ray powder diffraction (XRD), scanning electron microscopy (SEM), and field emission scanning electron microscopy (FE-SEM). The results revealed that the highly crystalline alpha-Fe2O3 submicro-flowers were composed of nanospheres with an average size of 20-30 nm. The electrochemical performance as anode material for lithium-ion batteries was further evaluated by Cyclic voltammetry (CV) and by electrochemical impedance and charge-discharge measurements. It was demonstrated that the material could provide an initial reversible capacity of 959.6 mAh/g at a current density of 20 mA/g over the voltage range from 0.0 1 to 3.0 V. The capacity retention upon the 50th cycle was 44.4 and 35.9% at 60 and 100 mA/g, respectively. The superior electrochemical performance may be resulted from the high surface area and the small and uniform grain size.

Authors


  •   Nuli, Yanna (external author)
  •   Zhang, Peng (external author)
  •   Guo, Zaiping
  •   Munroe, Paul R. (external author)
  •   Liu, Hua K.

Publication Date


  • 2008

Citation


  • Nuli, Y., Zhang, P., Guo, Z., Munroe, P. G. & Liu, H. K. (2008). Preparation of alpha-Fe2O3 submicro-flowers by a hydrothermal approach and their electrochemical performance in lithium-ion batteries. Electrochimica Acta, 53 (12), 4213-4218.

Scopus Eid


  • 2-s2.0-40149103249

Ro Metadata Url


  • http://ro.uow.edu.au/engpapers/3446

Has Global Citation Frequency


Number Of Pages


  • 5

Start Page


  • 4213

End Page


  • 4218

Volume


  • 53

Issue


  • 12

Abstract


  • Uniform alpha-Fe2O3 submicron-sized flowers have been synthesized by a simple hydrothermal process conducted at 160 degrees C for 024 h. The crystalline structure and morphology of the as-synthesized powder have been characterized by using X-ray powder diffraction (XRD), scanning electron microscopy (SEM), and field emission scanning electron microscopy (FE-SEM). The results revealed that the highly crystalline alpha-Fe2O3 submicro-flowers were composed of nanospheres with an average size of 20-30 nm. The electrochemical performance as anode material for lithium-ion batteries was further evaluated by Cyclic voltammetry (CV) and by electrochemical impedance and charge-discharge measurements. It was demonstrated that the material could provide an initial reversible capacity of 959.6 mAh/g at a current density of 20 mA/g over the voltage range from 0.0 1 to 3.0 V. The capacity retention upon the 50th cycle was 44.4 and 35.9% at 60 and 100 mA/g, respectively. The superior electrochemical performance may be resulted from the high surface area and the small and uniform grain size.

Authors


  •   Nuli, Yanna (external author)
  •   Zhang, Peng (external author)
  •   Guo, Zaiping
  •   Munroe, Paul R. (external author)
  •   Liu, Hua K.

Publication Date


  • 2008

Citation


  • Nuli, Y., Zhang, P., Guo, Z., Munroe, P. G. & Liu, H. K. (2008). Preparation of alpha-Fe2O3 submicro-flowers by a hydrothermal approach and their electrochemical performance in lithium-ion batteries. Electrochimica Acta, 53 (12), 4213-4218.

Scopus Eid


  • 2-s2.0-40149103249

Ro Metadata Url


  • http://ro.uow.edu.au/engpapers/3446

Has Global Citation Frequency


Number Of Pages


  • 5

Start Page


  • 4213

End Page


  • 4218

Volume


  • 53

Issue


  • 12