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General Synthesis of Single-Atom Catalysts for Hydrogen Evolution Reactions and Room-Temperature Na-S Batteries

Journal Article


Abstract


  • © 2020 Wiley-VCH GmbH Herein, we report a comprehensive strategy to synthesize a full range of single-atom metals on carbon matrix, including V, Mn, Fe, Co, Ni, Cu, Ge, Mo, Ru, Rh, Pd, Ag, In, Sn, W, Ir, Pt, Pb, and Bi. The extensive applications of various SACs are manifested via their ability to electro-catalyze typical hydrogen evolution reactions (HER) and conversion reactions in novel room-temperature sodium sulfur batteries (RT-Na-S). The enhanced performances for these electrochemical reactions arisen from the ability of different single active atoms on local structures to tune their electronic configuration. Significantly, the electrocatalytic behaviors of diverse SACs, assisted by density functional theory calculations, are systematically revealed by in situ synchrotron X-ray diffraction and in situ transmission electronic microscopy, providing a strategic library for the general synthesis and extensive applications of SACs in energy conversion and storage.

Authors


  •   Lai, Weihong (external author)
  •   Wang, Heng (external author)
  •   Zheng, Lirong (external author)
  •   Jiang, Quan (external author)
  •   Yan, Zi (external author)
  •   Wang, Lei (external author)
  •   Yoshikawa, Hirofumi (external author)
  •   Matsumura, Daiju (external author)
  •   Sun, Qiao (external author)
  •   Wang, Yun-Xiao
  •   Gu, Qinfen (external author)
  •   Wang, Jiazhao
  •   Liu, Hua K.
  •   Chou, Shulei
  •   Dou, Shi Xue

Publication Date


  • 2020

Citation


  • Lai, W., Wang, H., Zheng, L., Jiang, Q., Yan, Z., Wang, L., Yoshikawa, H., Matsumura, D., Sun, Q., Wang, Y., Gu, Q., Wang, J., Liu, H., Chou, S. & Dou, S. (2020). General Synthesis of Single-Atom Catalysts for Hydrogen Evolution Reactions and Room-Temperature Na-S Batteries. Angewandte Chemie - International Edition,
  • Lai, W., Wang, H., Zheng, L., Jiang, Q., Yan, Z., Wang, L., Yoshikawa, H., Matsumura, D., Sun, Q., Wang, Y., Gu, Q., Wang, J., Liu, H., Chou, S. & Dou, S. (2020). General Synthesis of Single-Atom Catalysts for Hydrogen Evolution Reactions and Room-Temperature Na-S Batteries. Angewandte Chemie - International Edition,

Scopus Eid


  • 2-s2.0-85091281142

Ro Full-text Url


Ro Metadata Url


Has Global Citation Frequency


Volume


Place Of Publication


  • Germany

Abstract


  • © 2020 Wiley-VCH GmbH Herein, we report a comprehensive strategy to synthesize a full range of single-atom metals on carbon matrix, including V, Mn, Fe, Co, Ni, Cu, Ge, Mo, Ru, Rh, Pd, Ag, In, Sn, W, Ir, Pt, Pb, and Bi. The extensive applications of various SACs are manifested via their ability to electro-catalyze typical hydrogen evolution reactions (HER) and conversion reactions in novel room-temperature sodium sulfur batteries (RT-Na-S). The enhanced performances for these electrochemical reactions arisen from the ability of different single active atoms on local structures to tune their electronic configuration. Significantly, the electrocatalytic behaviors of diverse SACs, assisted by density functional theory calculations, are systematically revealed by in situ synchrotron X-ray diffraction and in situ transmission electronic microscopy, providing a strategic library for the general synthesis and extensive applications of SACs in energy conversion and storage.

Authors


  •   Lai, Weihong (external author)
  •   Wang, Heng (external author)
  •   Zheng, Lirong (external author)
  •   Jiang, Quan (external author)
  •   Yan, Zi (external author)
  •   Wang, Lei (external author)
  •   Yoshikawa, Hirofumi (external author)
  •   Matsumura, Daiju (external author)
  •   Sun, Qiao (external author)
  •   Wang, Yun-Xiao
  •   Gu, Qinfen (external author)
  •   Wang, Jiazhao
  •   Liu, Hua K.
  •   Chou, Shulei
  •   Dou, Shi Xue

Publication Date


  • 2020

Citation


  • Lai, W., Wang, H., Zheng, L., Jiang, Q., Yan, Z., Wang, L., Yoshikawa, H., Matsumura, D., Sun, Q., Wang, Y., Gu, Q., Wang, J., Liu, H., Chou, S. & Dou, S. (2020). General Synthesis of Single-Atom Catalysts for Hydrogen Evolution Reactions and Room-Temperature Na-S Batteries. Angewandte Chemie - International Edition,
  • Lai, W., Wang, H., Zheng, L., Jiang, Q., Yan, Z., Wang, L., Yoshikawa, H., Matsumura, D., Sun, Q., Wang, Y., Gu, Q., Wang, J., Liu, H., Chou, S. & Dou, S. (2020). General Synthesis of Single-Atom Catalysts for Hydrogen Evolution Reactions and Room-Temperature Na-S Batteries. Angewandte Chemie - International Edition,

Scopus Eid


  • 2-s2.0-85091281142

Ro Full-text Url


Ro Metadata Url


Has Global Citation Frequency


Volume


Place Of Publication


  • Germany