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Super‐Kinetically Pseudocapacitive MnCo2S4 Nanourchins toward High‐Rate and Highly Stable Sodium‐Ion Storage

Journal Article


Abstract


  • © 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim Improving surface morphology profiles, i.e., surface area and porosity, by nanostructure/surface engineering is effective in accommodating sodium's ionic and kinetic inadequacies. However, this strategy is limited to only activating the extrinsic pseudocapacitance in terms of improving surface-based reactions. Herein, it is aimed to improve the sodiation performance by enhancement from both intrinsic and extrinsic pseudocapacitance to maximize sodiation potential of materials. A rarely reported but highly functional spinel MnCo2S4 (MCS), is introduced and systematically analyzed using first-principles investigations, which exhibits energetically favorable charge-transfer states and strong Na-ions adsorption kinetics as well as diffusion channels (−3.65 and 0.40 eV respectively). The overall electrochemical redox profiles of the MCS nanostructure is revealed by in situ techniques, which disclose the commencing of partial and then a full conversion-type sodiation at low discharge potentials (0.52 V vs Na/Na+) with fast Na-ions diffusivity. Assisted by surface engineering technology on the intrinsically pseudocapacitive MCS, the urchin-like morphology is instrumental in boosting and realizing sodium storage performance, especially the surface capacitive behavior (from 73.4% to 94.1%), prolonged cycling stability (>800 cycles), and high-rate capability (416 mAh g−1 at 10 A g−1), as well as exhibiting remarkable full cell capability (high rate at 2 A g−1, >200 cycles at 200 mA g−1).

Authors


  •   Lim, Yew (external author)
  •   Huang, Shaozhuan (external author)
  •   Wu, Qingyun (external author)
  •   Kong, Dezhi (external author)
  •   Wang, Ye (external author)
  •   Zhu, Yanfang (external author)
  •   Wang, Yanxia (external author)
  •   Wang, Yun-Xiao
  •   Liu, Hua K.
  •   Dou, Shi Xue
  •   Ang, Lay (external author)
  •   Yang, Hui (external author)

Publication Date


  • 2020

Citation


  • Lim, Y., Huang, S., Wu, Q., Kong, D., Wang, Y., Zhu, Y., Wang, Y., Wang, Y., Liu, H., Dou, S., Ang, L. & Yang, H. (2020). Super‐Kinetically Pseudocapacitive MnCo2S4 Nanourchins toward High‐Rate and Highly Stable Sodium‐Ion Storage. Advanced Functional Materials,

Scopus Eid


  • 2-s2.0-85079557282

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/4038

Place Of Publication


  • Germany

Abstract


  • © 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim Improving surface morphology profiles, i.e., surface area and porosity, by nanostructure/surface engineering is effective in accommodating sodium's ionic and kinetic inadequacies. However, this strategy is limited to only activating the extrinsic pseudocapacitance in terms of improving surface-based reactions. Herein, it is aimed to improve the sodiation performance by enhancement from both intrinsic and extrinsic pseudocapacitance to maximize sodiation potential of materials. A rarely reported but highly functional spinel MnCo2S4 (MCS), is introduced and systematically analyzed using first-principles investigations, which exhibits energetically favorable charge-transfer states and strong Na-ions adsorption kinetics as well as diffusion channels (−3.65 and 0.40 eV respectively). The overall electrochemical redox profiles of the MCS nanostructure is revealed by in situ techniques, which disclose the commencing of partial and then a full conversion-type sodiation at low discharge potentials (0.52 V vs Na/Na+) with fast Na-ions diffusivity. Assisted by surface engineering technology on the intrinsically pseudocapacitive MCS, the urchin-like morphology is instrumental in boosting and realizing sodium storage performance, especially the surface capacitive behavior (from 73.4% to 94.1%), prolonged cycling stability (>800 cycles), and high-rate capability (416 mAh g−1 at 10 A g−1), as well as exhibiting remarkable full cell capability (high rate at 2 A g−1, >200 cycles at 200 mA g−1).

Authors


  •   Lim, Yew (external author)
  •   Huang, Shaozhuan (external author)
  •   Wu, Qingyun (external author)
  •   Kong, Dezhi (external author)
  •   Wang, Ye (external author)
  •   Zhu, Yanfang (external author)
  •   Wang, Yanxia (external author)
  •   Wang, Yun-Xiao
  •   Liu, Hua K.
  •   Dou, Shi Xue
  •   Ang, Lay (external author)
  •   Yang, Hui (external author)

Publication Date


  • 2020

Citation


  • Lim, Y., Huang, S., Wu, Q., Kong, D., Wang, Y., Zhu, Y., Wang, Y., Wang, Y., Liu, H., Dou, S., Ang, L. & Yang, H. (2020). Super‐Kinetically Pseudocapacitive MnCo2S4 Nanourchins toward High‐Rate and Highly Stable Sodium‐Ion Storage. Advanced Functional Materials,

Scopus Eid


  • 2-s2.0-85079557282

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/4038

Place Of Publication


  • Germany