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Multiple Anionic Transition-Metal Oxycarbide for Better Lithium Storage and Facilitated Multielectron Reactions

Journal Article


Abstract


  • As an important class of multielectron reaction materials, the applications of transition-metal oxides (TMOs) are impeded by volume expansion and poor electrochemical activity. To address these intrinsic limitations, the renewal of TMOs inspires research on incorporating an advanced interface layer with multiple anionic characteristics, which may add functionality to support properties inaccessible to a single-anion TMO electrode. Herein, a transition-metal oxycarbide (TMOC, M = Mo) with more than one anionic species was prepared as an interface layer on a corresponding oxide. A multiple anionic TMOC possesses advantages of structural stability, abundant active sites, and elevated metal cation valence states. Such merits mitigate volume changes and enhance multielectron reactions significantly. The TMOC nanocomposite has a well-maintained capacity after 1000 cycles at 2 A·g-1 and fully resumed rate performance. In situ synchrotron X-ray powder diffraction (SXRPD) analysis unveils negligible volume expansions occurring upon oxycarbide layer coupling, with lattice spacing variation less than 1% during cycling. The lithium storage mechanism is further inspected by combined analysis of kinetics, SXRPD, and first-principles calculations. Superior to TMO, multielectron reactions of the TMOC electrode have been boosted due to easier rupture of the metal-oxygen bond. Such improvements underscore the importance of incorporating an oxycarbide configuration as a strategy to expand applications of TMOs.

Authors


  •   Cuan, Jing (external author)
  •   Zhou, You (external author)
  •   Zhang, Jian (external author)
  •   Zhou, Tengfei
  •   Liang, Gemeng (external author)
  •   Li, Sean (external author)
  •   Yu, Xuebin (external author)
  •   Pang, Wei Kong.
  •   Guo, Zaiping

Publication Date


  • 2019

Citation


  • Cuan, J., Zhou, Y., Zhang, J., Zhou, T., Liang, G., Li, S., Yu, X., Pang, W. & Guo, Z. (2019). Multiple Anionic Transition-Metal Oxycarbide for Better Lithium Storage and Facilitated Multielectron Reactions. ACS Nano, 13 (10), 11665-11675.

Scopus Eid


  • 2-s2.0-85072942413

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/3867

Has Global Citation Frequency


Number Of Pages


  • 10

Start Page


  • 11665

End Page


  • 11675

Volume


  • 13

Issue


  • 10

Place Of Publication


  • United States

Abstract


  • As an important class of multielectron reaction materials, the applications of transition-metal oxides (TMOs) are impeded by volume expansion and poor electrochemical activity. To address these intrinsic limitations, the renewal of TMOs inspires research on incorporating an advanced interface layer with multiple anionic characteristics, which may add functionality to support properties inaccessible to a single-anion TMO electrode. Herein, a transition-metal oxycarbide (TMOC, M = Mo) with more than one anionic species was prepared as an interface layer on a corresponding oxide. A multiple anionic TMOC possesses advantages of structural stability, abundant active sites, and elevated metal cation valence states. Such merits mitigate volume changes and enhance multielectron reactions significantly. The TMOC nanocomposite has a well-maintained capacity after 1000 cycles at 2 A·g-1 and fully resumed rate performance. In situ synchrotron X-ray powder diffraction (SXRPD) analysis unveils negligible volume expansions occurring upon oxycarbide layer coupling, with lattice spacing variation less than 1% during cycling. The lithium storage mechanism is further inspected by combined analysis of kinetics, SXRPD, and first-principles calculations. Superior to TMO, multielectron reactions of the TMOC electrode have been boosted due to easier rupture of the metal-oxygen bond. Such improvements underscore the importance of incorporating an oxycarbide configuration as a strategy to expand applications of TMOs.

Authors


  •   Cuan, Jing (external author)
  •   Zhou, You (external author)
  •   Zhang, Jian (external author)
  •   Zhou, Tengfei
  •   Liang, Gemeng (external author)
  •   Li, Sean (external author)
  •   Yu, Xuebin (external author)
  •   Pang, Wei Kong.
  •   Guo, Zaiping

Publication Date


  • 2019

Citation


  • Cuan, J., Zhou, Y., Zhang, J., Zhou, T., Liang, G., Li, S., Yu, X., Pang, W. & Guo, Z. (2019). Multiple Anionic Transition-Metal Oxycarbide for Better Lithium Storage and Facilitated Multielectron Reactions. ACS Nano, 13 (10), 11665-11675.

Scopus Eid


  • 2-s2.0-85072942413

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/3867

Has Global Citation Frequency


Number Of Pages


  • 10

Start Page


  • 11665

End Page


  • 11675

Volume


  • 13

Issue


  • 10

Place Of Publication


  • United States