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Ultrafast Li-ion migration in holey-graphene-based composites constructed by a generalized: Ex situ method towards high capacity energy storage

Journal Article


Abstract


  • Holey graphene is regarded as a promising upgrade of graphene in energy storage devices to expedite ion migration, but the scant surface groups of holey graphene hinder the in situ growth of electroactive materials, severely challenging its hybridization and further applications. Here we report a facile and generalized ex situ methodology to integrate various promising electroactive materials (e.g., Fe 3 O 4 , SnO 2 , MnO, and MoS 2 ) on holey graphene, with ultrafine particle size and highly controllable loading contents. For example, monodisperse Fe 3 O 4 nanoparticles (ca. 10 nm) with a high loading of up to 79 wt% are uniformly distributed on the highly interconnected holey graphene network. As an anode for lithium-ion batteries, the Fe 3 O 4 /holey-graphene composite (Fe 3 O 4 @3DhG) achieves 1516 mA h g -1 at 0.2 A g -1 , and 554 mA h g -1 at 5.0 A g -1 for over 2500 cycles, exhibiting extremely high capacity, excellent rate performance, and marvelous cycling longevity. It is demonstrated that the conductive and hierarchically porous holey graphene backbones can not only facilitate the ion-/electron-transmission and accommodate the volume changes upon lithiation/delithiation, but also activate the surface-controlled capacitive effect to a transnormal level. Moreover, the outstanding performance of the full cells with LiFePO 4 cathodes and Fe 3 O 4 @3DhG anodes reveals the immense potential in commercialization of such composites.

Authors


  •   Zhu, Chengling (external author)
  •   Hui, Zeyu (external author)
  •   Pan, Hui (external author)
  •   Zhu, Shenmin (external author)
  •   Zhang, Qing (external author)
  •   Mao, Jianfeng
  •   Guo, Zaiping
  •   Li, Yao (external author)
  •   Imtiaz, Muhammad (external author)
  •   Chen, Zhixin

Publication Date


  • 2019

Citation


  • Zhu, C., Hui, Z., Pan, H., Zhu, S., Zhang, Q., Mao, J., Guo, Z., Li, Y., Imtiaz, M. & Chen, Z. (2019). Ultrafast Li-ion migration in holey-graphene-based composites constructed by a generalized: Ex situ method towards high capacity energy storage. Journal of Materials Chemistry A, 7 (9), 4788-4796.

Scopus Eid


  • 2-s2.0-85062299769

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/3496

Number Of Pages


  • 8

Start Page


  • 4788

End Page


  • 4796

Volume


  • 7

Issue


  • 9

Place Of Publication


  • United Kingdom

Abstract


  • Holey graphene is regarded as a promising upgrade of graphene in energy storage devices to expedite ion migration, but the scant surface groups of holey graphene hinder the in situ growth of electroactive materials, severely challenging its hybridization and further applications. Here we report a facile and generalized ex situ methodology to integrate various promising electroactive materials (e.g., Fe 3 O 4 , SnO 2 , MnO, and MoS 2 ) on holey graphene, with ultrafine particle size and highly controllable loading contents. For example, monodisperse Fe 3 O 4 nanoparticles (ca. 10 nm) with a high loading of up to 79 wt% are uniformly distributed on the highly interconnected holey graphene network. As an anode for lithium-ion batteries, the Fe 3 O 4 /holey-graphene composite (Fe 3 O 4 @3DhG) achieves 1516 mA h g -1 at 0.2 A g -1 , and 554 mA h g -1 at 5.0 A g -1 for over 2500 cycles, exhibiting extremely high capacity, excellent rate performance, and marvelous cycling longevity. It is demonstrated that the conductive and hierarchically porous holey graphene backbones can not only facilitate the ion-/electron-transmission and accommodate the volume changes upon lithiation/delithiation, but also activate the surface-controlled capacitive effect to a transnormal level. Moreover, the outstanding performance of the full cells with LiFePO 4 cathodes and Fe 3 O 4 @3DhG anodes reveals the immense potential in commercialization of such composites.

Authors


  •   Zhu, Chengling (external author)
  •   Hui, Zeyu (external author)
  •   Pan, Hui (external author)
  •   Zhu, Shenmin (external author)
  •   Zhang, Qing (external author)
  •   Mao, Jianfeng
  •   Guo, Zaiping
  •   Li, Yao (external author)
  •   Imtiaz, Muhammad (external author)
  •   Chen, Zhixin

Publication Date


  • 2019

Citation


  • Zhu, C., Hui, Z., Pan, H., Zhu, S., Zhang, Q., Mao, J., Guo, Z., Li, Y., Imtiaz, M. & Chen, Z. (2019). Ultrafast Li-ion migration in holey-graphene-based composites constructed by a generalized: Ex situ method towards high capacity energy storage. Journal of Materials Chemistry A, 7 (9), 4788-4796.

Scopus Eid


  • 2-s2.0-85062299769

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/3496

Number Of Pages


  • 8

Start Page


  • 4788

End Page


  • 4796

Volume


  • 7

Issue


  • 9

Place Of Publication


  • United Kingdom