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Microporous materials formed via intercalation of ultrathin coordination polymers in a layered silicate

Journal Article


Abstract


  • Development of microporous materials, like zeolites and metal-organic frameworks (MOFs), with unique and better properties, is crucially important, while yet challenging, for many energy applications. Herein, we report on a new family of microporous hybrids having well-defined permanent porosity, which is formed by pillaring a layered silicate with packed coordination polymers. This inorganic-organic hybrid material, having well-defined/two-faced micropores surrounded by the polymers and silicate walls, exhibits superior adsorption toward methanol due to co-operative interactions compared with conventional microporous materials. The material could be used as an adsorbent to selectively and effectively recover methanol from a methanol/water vapour mixture.

Authors


  •   Ide, Yusuke (external author)
  •   Tominaka, Satoshi (external author)
  •   Okuyama, Taiki (external author)
  •   Tsunoji, Nao (external author)
  •   Ohara, Koji (external author)
  •   Mitome, Masanori (external author)
  •   Sano, Tsuneji (external author)
  •   Bando, Yoshio
  •   Golberg, Dmitri (external author)

Publication Date


  • 2019

Citation


  • Ide, Y., Tominaka, S., Okuyama, T., Tsunoji, N., Ohara, K., Mitome, M., Sano, T., Bando, Y. & Golberg, D. (2019). Microporous materials formed via intercalation of ultrathin coordination polymers in a layered silicate. Nano Energy, 59 162-168.

Scopus Eid


  • 2-s2.0-85061815014

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/3470

Number Of Pages


  • 6

Start Page


  • 162

End Page


  • 168

Volume


  • 59

Place Of Publication


  • Netherlands

Abstract


  • Development of microporous materials, like zeolites and metal-organic frameworks (MOFs), with unique and better properties, is crucially important, while yet challenging, for many energy applications. Herein, we report on a new family of microporous hybrids having well-defined permanent porosity, which is formed by pillaring a layered silicate with packed coordination polymers. This inorganic-organic hybrid material, having well-defined/two-faced micropores surrounded by the polymers and silicate walls, exhibits superior adsorption toward methanol due to co-operative interactions compared with conventional microporous materials. The material could be used as an adsorbent to selectively and effectively recover methanol from a methanol/water vapour mixture.

Authors


  •   Ide, Yusuke (external author)
  •   Tominaka, Satoshi (external author)
  •   Okuyama, Taiki (external author)
  •   Tsunoji, Nao (external author)
  •   Ohara, Koji (external author)
  •   Mitome, Masanori (external author)
  •   Sano, Tsuneji (external author)
  •   Bando, Yoshio
  •   Golberg, Dmitri (external author)

Publication Date


  • 2019

Citation


  • Ide, Y., Tominaka, S., Okuyama, T., Tsunoji, N., Ohara, K., Mitome, M., Sano, T., Bando, Y. & Golberg, D. (2019). Microporous materials formed via intercalation of ultrathin coordination polymers in a layered silicate. Nano Energy, 59 162-168.

Scopus Eid


  • 2-s2.0-85061815014

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/3470

Number Of Pages


  • 6

Start Page


  • 162

End Page


  • 168

Volume


  • 59

Place Of Publication


  • Netherlands