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Polyoxygenated Cyclohexenes and Their Chlorinated Derivatives from the Leaves of Uvaria cherrevensis

Journal Article


Abstract


  • The chemical study of leaf extracts from Uvaria cherrevensis resulted in the identification of 11 new polyoxygenated cyclohexenes, cherrevenols A-K (1-11), and a new seco-cyclohexene derivative, cherrevenol L (12). Nine known compounds (13-21) were also isolated. Three of the isolated compounds are chlorinated polyoxygenated cyclohexenes. The structures of these compounds were determined using spectroscopic methods and, in some cases (compounds 2, 6, 8, and 10), single-crystal X-ray crystallographic structural analysis or chemical correlation (compounds 6 and 7). Compounds 6 and 7 were both isolated as scalemic mixtures (ee 23-24%).

UOW Authors


  •   Auranwiwat, Chiramet (external author)
  •   Wongsomboon, Puttandon (external author)
  •   Thaima, Thanaphat (external author)
  •   Rattanajak, Roonglawan (external author)
  •   Kamchonwongpaisan, Sumalee (external author)
  •   Willis, Anthony C. (external author)
  •   Laphookhieo, Surat (external author)
  •   Pyne, Stephen
  •   Limtharakul, Thunwadee (external author)

Publication Date


  • 2019

Citation


  • Auranwiwat, C., Wongsomboon, P., Thaima, T., Rattanajak, R., Kamchonwongpaisan, S., Willis, A. C., Laphookhieo, S., Pyne, S. G. & Limtharakul, T. (2019). Polyoxygenated Cyclohexenes and Their Chlorinated Derivatives from the Leaves of Uvaria cherrevensis. Journal of Natural Products, 82 (1), 101-110.

Scopus Eid


  • 2-s2.0-85060556746

Number Of Pages


  • 9

Start Page


  • 101

End Page


  • 110

Volume


  • 82

Issue


  • 1

Place Of Publication


  • United States

Abstract


  • The chemical study of leaf extracts from Uvaria cherrevensis resulted in the identification of 11 new polyoxygenated cyclohexenes, cherrevenols A-K (1-11), and a new seco-cyclohexene derivative, cherrevenol L (12). Nine known compounds (13-21) were also isolated. Three of the isolated compounds are chlorinated polyoxygenated cyclohexenes. The structures of these compounds were determined using spectroscopic methods and, in some cases (compounds 2, 6, 8, and 10), single-crystal X-ray crystallographic structural analysis or chemical correlation (compounds 6 and 7). Compounds 6 and 7 were both isolated as scalemic mixtures (ee 23-24%).

UOW Authors


  •   Auranwiwat, Chiramet (external author)
  •   Wongsomboon, Puttandon (external author)
  •   Thaima, Thanaphat (external author)
  •   Rattanajak, Roonglawan (external author)
  •   Kamchonwongpaisan, Sumalee (external author)
  •   Willis, Anthony C. (external author)
  •   Laphookhieo, Surat (external author)
  •   Pyne, Stephen
  •   Limtharakul, Thunwadee (external author)

Publication Date


  • 2019

Citation


  • Auranwiwat, C., Wongsomboon, P., Thaima, T., Rattanajak, R., Kamchonwongpaisan, S., Willis, A. C., Laphookhieo, S., Pyne, S. G. & Limtharakul, T. (2019). Polyoxygenated Cyclohexenes and Their Chlorinated Derivatives from the Leaves of Uvaria cherrevensis. Journal of Natural Products, 82 (1), 101-110.

Scopus Eid


  • 2-s2.0-85060556746

Number Of Pages


  • 9

Start Page


  • 101

End Page


  • 110

Volume


  • 82

Issue


  • 1

Place Of Publication


  • United States