Abstract
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Platinum (Pt) is known as one of the most promising
electrocatalysts, and nanostructured Pt materials have enhanced
its activity due to their abundant catalytically active sites
derived from their high surface area. Herein, we synthesize
fascinating dendritic Pt nanoparticles (DPNs) by a softtemplating
method using hexadecyltrimethylammonium chloride
(CTAC) as a pore-forming agent. The dissolved negatively
charged Pt precursor (PtCl4
2¹) effectively interact with the
surfactant. The particle size of the obtained DPNs is around
20 nm, and the pore walls are composed of Pt nanocrystals. The
obtained DPNs show good electrocatalytic activity towards
methanol oxidation reaction (MOR) compared to commercial
Pt black (PtB), and its stability is also higher than that of PtB