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NDACC harmonized formaldehyde time series from 21 FTIR stations covering a wide range of column abundances

Journal Article


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Abstract


  • Among the more than 20 ground-based FTIR (Fourier transform infrared) stations currently operating around the globe, only a few have provided formaldehyde (HCHO) total column time series until now. Although several independent studies have shown that the FTIR measurements can provide formaldehyde total columns with good precision, the spatial coverage has not been optimal for providing good diagnostics for satellite or model validation. Furthermore, these past studies used different retrieval settings, and biases as large as 50% can be observed in the HCHO total columns depending on these retrieval choices, which is also a weakness for validation studies combining data from different ground-based stations. For the present work, the HCHO retrieval settings have been optimized based on experience gained from past studies and have been applied consistently at the 21 participating stations. Most of them are either part of the Network for the Detection of Atmospheric Composition Change (NDACC) or under consideration for membership. We provide the harmonized settings and a characterization of the HCHO FTIR products. Depending on the station, the total systematic and random uncertainties of an individual HCHO total column measurement lie between 12% and 27% and between 1 and 11×1014moleccm-2, respectively. The median values among all stations are 13% and 2.9×1014moleccm-2 for the total systematic and random uncertainties. This unprecedented harmonized formaldehyde data set from 21 ground-based FTIR stations is presented and its comparison with a global chemistry transport model shows consistency in absolute values as well as in seasonal cycles. The network covers very different concentration levels of formaldehyde, from very clean levels at the limit of detection (few 1013moleccm-2) to highly polluted levels (7×1016moleccm-2). Because the measurements can be made at any time during daylight, the diurnal cycle can be observed and is found to be significant at many stations. These HCHO time series, some of them starting in the 1990s, are crucial for past and present satellite validation and will be extended in the coming years for the next generation of satellite missions.

Authors


  •   Vigouroux, C (external author)
  •   Bauer Aquino, Carlos Augusto (external author)
  •   Bauwens, Maite (external author)
  •   Becker, Cornelis (external author)
  •   Blumenstock, Thomas (external author)
  •   de Maziere, Martine (external author)
  •   Garcia, Omar E. (external author)
  •   Grutter, Michel (external author)
  •   Guarin, Cesar (external author)
  •   Hannigan, James W. (external author)
  •   Hase, Frank (external author)
  •   Jones, Nicholas B.
  •   Kivi, Rigel (external author)
  •   Koshelev, Dmitry (external author)
  •   Langerock, Bavo (external author)
  •   Lutsch, Erik (external author)
  •   Makarova, M V. (external author)
  •   Metzger, J -M. (external author)
  •   Muller, Jean François. (external author)
  •   Notholt, Justus (external author)
  •   Ortega, Ivan (external author)
  •   Palm, Mathias (external author)
  •   Clare Murphy (Paton-Walsh)
  •   Poberovskii, A M. (external author)
  •   Rettinger, Markus (external author)
  •   Robinson, John (external author)
  •   Smale, D (external author)
  •   Stavrakou, Trissevgeni (external author)
  •   Stremme, Wolfgang (external author)
  •   Strong, Kimberly (external author)
  •   Sussmann, Ralf (external author)
  •   Te, Yao (external author)
  •   Toon, Geoffrey C. (external author)

Publication Date


  • 2018

Citation


  • Vigouroux, C., Bauer Aquino, C., Bauwens, M., Becker, C., Blumenstock, T., de Maziere, M., Garcia, O., Grutter, M., Guarin, C., Hannigan, J., Hase, F., Jones, N., Kivi, R., Koshelev, D., Langerock, B., Lutsch, E., Makarova, M., Metzger, J., Muller, J., Notholt, J., Ortega, I., Palm, M., Paton-Walsh, C., Poberovskii, A., Rettinger, M., Robinson, J., Smale, D., Stavrakou, T., Stremme, W., Strong, K., Sussmann, R., Te, Y. & Toon, G. (2018). NDACC harmonized formaldehyde time series from 21 FTIR stations covering a wide range of column abundances. Atmospheric Measurement Techniques, 11 (9), 5049-5073.

Scopus Eid


  • 2-s2.0-85053032489

Ro Full-text Url


  • https://ro.uow.edu.au/cgi/viewcontent.cgi?article=1194&context=smhpapers1

Ro Metadata Url


  • http://ro.uow.edu.au/smhpapers1/191

Number Of Pages


  • 24

Start Page


  • 5049

End Page


  • 5073

Volume


  • 11

Issue


  • 9

Place Of Publication


  • Germany

Abstract


  • Among the more than 20 ground-based FTIR (Fourier transform infrared) stations currently operating around the globe, only a few have provided formaldehyde (HCHO) total column time series until now. Although several independent studies have shown that the FTIR measurements can provide formaldehyde total columns with good precision, the spatial coverage has not been optimal for providing good diagnostics for satellite or model validation. Furthermore, these past studies used different retrieval settings, and biases as large as 50% can be observed in the HCHO total columns depending on these retrieval choices, which is also a weakness for validation studies combining data from different ground-based stations. For the present work, the HCHO retrieval settings have been optimized based on experience gained from past studies and have been applied consistently at the 21 participating stations. Most of them are either part of the Network for the Detection of Atmospheric Composition Change (NDACC) or under consideration for membership. We provide the harmonized settings and a characterization of the HCHO FTIR products. Depending on the station, the total systematic and random uncertainties of an individual HCHO total column measurement lie between 12% and 27% and between 1 and 11×1014moleccm-2, respectively. The median values among all stations are 13% and 2.9×1014moleccm-2 for the total systematic and random uncertainties. This unprecedented harmonized formaldehyde data set from 21 ground-based FTIR stations is presented and its comparison with a global chemistry transport model shows consistency in absolute values as well as in seasonal cycles. The network covers very different concentration levels of formaldehyde, from very clean levels at the limit of detection (few 1013moleccm-2) to highly polluted levels (7×1016moleccm-2). Because the measurements can be made at any time during daylight, the diurnal cycle can be observed and is found to be significant at many stations. These HCHO time series, some of them starting in the 1990s, are crucial for past and present satellite validation and will be extended in the coming years for the next generation of satellite missions.

Authors


  •   Vigouroux, C (external author)
  •   Bauer Aquino, Carlos Augusto (external author)
  •   Bauwens, Maite (external author)
  •   Becker, Cornelis (external author)
  •   Blumenstock, Thomas (external author)
  •   de Maziere, Martine (external author)
  •   Garcia, Omar E. (external author)
  •   Grutter, Michel (external author)
  •   Guarin, Cesar (external author)
  •   Hannigan, James W. (external author)
  •   Hase, Frank (external author)
  •   Jones, Nicholas B.
  •   Kivi, Rigel (external author)
  •   Koshelev, Dmitry (external author)
  •   Langerock, Bavo (external author)
  •   Lutsch, Erik (external author)
  •   Makarova, M V. (external author)
  •   Metzger, J -M. (external author)
  •   Muller, Jean François. (external author)
  •   Notholt, Justus (external author)
  •   Ortega, Ivan (external author)
  •   Palm, Mathias (external author)
  •   Clare Murphy (Paton-Walsh)
  •   Poberovskii, A M. (external author)
  •   Rettinger, Markus (external author)
  •   Robinson, John (external author)
  •   Smale, D (external author)
  •   Stavrakou, Trissevgeni (external author)
  •   Stremme, Wolfgang (external author)
  •   Strong, Kimberly (external author)
  •   Sussmann, Ralf (external author)
  •   Te, Yao (external author)
  •   Toon, Geoffrey C. (external author)

Publication Date


  • 2018

Citation


  • Vigouroux, C., Bauer Aquino, C., Bauwens, M., Becker, C., Blumenstock, T., de Maziere, M., Garcia, O., Grutter, M., Guarin, C., Hannigan, J., Hase, F., Jones, N., Kivi, R., Koshelev, D., Langerock, B., Lutsch, E., Makarova, M., Metzger, J., Muller, J., Notholt, J., Ortega, I., Palm, M., Paton-Walsh, C., Poberovskii, A., Rettinger, M., Robinson, J., Smale, D., Stavrakou, T., Stremme, W., Strong, K., Sussmann, R., Te, Y. & Toon, G. (2018). NDACC harmonized formaldehyde time series from 21 FTIR stations covering a wide range of column abundances. Atmospheric Measurement Techniques, 11 (9), 5049-5073.

Scopus Eid


  • 2-s2.0-85053032489

Ro Full-text Url


  • https://ro.uow.edu.au/cgi/viewcontent.cgi?article=1194&context=smhpapers1

Ro Metadata Url


  • http://ro.uow.edu.au/smhpapers1/191

Number Of Pages


  • 24

Start Page


  • 5049

End Page


  • 5073

Volume


  • 11

Issue


  • 9

Place Of Publication


  • Germany