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Origin of low dielectric loss and giant dielectric response in (Nb+Al) co-doped strontium titanate

Journal Article


Abstract


  • (Nb+Al) co-doped SrTiO3ceramics with a nominal composition of Sr(Nb0.5Al0.5)xTi1-xO3(x = 0, 0.02, 0.04, and 0.06) were fabricated using the conventional solid-state reaction method; giant permittivity (10500) and low dielectric loss (0.03) were obtained at x = 0.06. Dielectric and impedance spectroscopy, X-ray photoelectron spectroscopy, and Raman spectroscopy, were employed to study why the dielectric property improved. The results indicate that the giant dielectric response occurs because of the combined effects of the off-center Ti3+reorientation and conduction of electrons with the polar ordering structure Ti3+/Ti4+. In contrast, the low dielectric loss can be attributed to electron localization that occurs because of the defect dipole SrTiO3. These fundamental understandings will benefit the design of doped SrTiO3ceramics with desired performance.

UOW Authors


  •   He, Zichen (external author)
  •   Cao, Minghe (external author)
  •   Zhou, Liang (external author)
  •   Zhang, Lin (external author)
  •   Xie, Juan (external author)
  •   Zhang, Shujun
  •   Qi, Junlei (external author)
  •   Hao, Hua (external author)
  •   Yao, Zhonghua (external author)
  •   Yu, Zhiyong (external author)
  •   Liu, Hanxing (external author)

Publication Date


  • 2018

Citation


  • He, Z., Cao, M., Zhou, L., Zhang, L., Xie, J., Zhang, S., Qi, J., Hao, H., Yao, Z., Yu, Z. & Liu, H. (2018). Origin of low dielectric loss and giant dielectric response in (Nb+Al) co-doped strontium titanate. Journal of the American Ceramic Society, 101 (11), 5089-5097.

Scopus Eid


  • 2-s2.0-85052886512

Number Of Pages


  • 8

Start Page


  • 5089

End Page


  • 5097

Volume


  • 101

Issue


  • 11

Abstract


  • (Nb+Al) co-doped SrTiO3ceramics with a nominal composition of Sr(Nb0.5Al0.5)xTi1-xO3(x = 0, 0.02, 0.04, and 0.06) were fabricated using the conventional solid-state reaction method; giant permittivity (10500) and low dielectric loss (0.03) were obtained at x = 0.06. Dielectric and impedance spectroscopy, X-ray photoelectron spectroscopy, and Raman spectroscopy, were employed to study why the dielectric property improved. The results indicate that the giant dielectric response occurs because of the combined effects of the off-center Ti3+reorientation and conduction of electrons with the polar ordering structure Ti3+/Ti4+. In contrast, the low dielectric loss can be attributed to electron localization that occurs because of the defect dipole SrTiO3. These fundamental understandings will benefit the design of doped SrTiO3ceramics with desired performance.

UOW Authors


  •   He, Zichen (external author)
  •   Cao, Minghe (external author)
  •   Zhou, Liang (external author)
  •   Zhang, Lin (external author)
  •   Xie, Juan (external author)
  •   Zhang, Shujun
  •   Qi, Junlei (external author)
  •   Hao, Hua (external author)
  •   Yao, Zhonghua (external author)
  •   Yu, Zhiyong (external author)
  •   Liu, Hanxing (external author)

Publication Date


  • 2018

Citation


  • He, Z., Cao, M., Zhou, L., Zhang, L., Xie, J., Zhang, S., Qi, J., Hao, H., Yao, Z., Yu, Z. & Liu, H. (2018). Origin of low dielectric loss and giant dielectric response in (Nb+Al) co-doped strontium titanate. Journal of the American Ceramic Society, 101 (11), 5089-5097.

Scopus Eid


  • 2-s2.0-85052886512

Number Of Pages


  • 8

Start Page


  • 5089

End Page


  • 5097

Volume


  • 101

Issue


  • 11