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Boosting potassium-ion batteries by few-layered composite anodes prepared via solution-triggered one-step shear exfoliation

Journal Article


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Abstract


  • Earth-abundant potassium is a promising alternative to lithium in rechargeable batteries, but a pivotal limitation of potassium-ion batteries is their relatively low capacity and poor cycling stability. Here, a high-performance potassium-ion battery is achieved by employing few-layered antimony sulfide/carbon sheet composite anode fabricated via one-step high-shear exfoliation in ethanol/water solvent. Antimony sulfide with few-layered structure minimizes the volume expansion during potassiation and shortens the ion transport pathways, thus enhancing the rate capability; while carbon sheets in the composite provide electrical conductivity and maintain the electrode cycling stability by trapping the inevitable by-product, elemental sulfur. Meanwhile, the effect of the exfoliation solvent on the fabrication of two-dimensional antimony sulfide/carbon is also investigated. It is found that water facilitates the exfoliation by lower diffusion barrier along the [010] direction of antimony sulfide, while ethanol in the solvent acts as the carbon source for in situ carbonization.

Publication Date


  • 2018

Citation


  • Liu, Y., Tai, Z., Zhang, J., Pang, W., Zhang, Q., Feng, H., Konstantinov, K., Guo, Z. & Liu, H. (2018). Boosting potassium-ion batteries by few-layered composite anodes prepared via solution-triggered one-step shear exfoliation. Nature Communications, 9 (1), 3645-1-3645-10.

Scopus Eid


  • 2-s2.0-85053008270

Ro Full-text Url


  • https://ro.uow.edu.au/cgi/viewcontent.cgi?article=4385&context=aiimpapers

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/3331

Start Page


  • 3645-1

End Page


  • 3645-10

Volume


  • 9

Issue


  • 1

Place Of Publication


  • United Kingdom

Abstract


  • Earth-abundant potassium is a promising alternative to lithium in rechargeable batteries, but a pivotal limitation of potassium-ion batteries is their relatively low capacity and poor cycling stability. Here, a high-performance potassium-ion battery is achieved by employing few-layered antimony sulfide/carbon sheet composite anode fabricated via one-step high-shear exfoliation in ethanol/water solvent. Antimony sulfide with few-layered structure minimizes the volume expansion during potassiation and shortens the ion transport pathways, thus enhancing the rate capability; while carbon sheets in the composite provide electrical conductivity and maintain the electrode cycling stability by trapping the inevitable by-product, elemental sulfur. Meanwhile, the effect of the exfoliation solvent on the fabrication of two-dimensional antimony sulfide/carbon is also investigated. It is found that water facilitates the exfoliation by lower diffusion barrier along the [010] direction of antimony sulfide, while ethanol in the solvent acts as the carbon source for in situ carbonization.

Publication Date


  • 2018

Citation


  • Liu, Y., Tai, Z., Zhang, J., Pang, W., Zhang, Q., Feng, H., Konstantinov, K., Guo, Z. & Liu, H. (2018). Boosting potassium-ion batteries by few-layered composite anodes prepared via solution-triggered one-step shear exfoliation. Nature Communications, 9 (1), 3645-1-3645-10.

Scopus Eid


  • 2-s2.0-85053008270

Ro Full-text Url


  • https://ro.uow.edu.au/cgi/viewcontent.cgi?article=4385&context=aiimpapers

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/3331

Start Page


  • 3645-1

End Page


  • 3645-10

Volume


  • 9

Issue


  • 1

Place Of Publication


  • United Kingdom