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Wheat flour-derived N-doped mesoporous carbon extrudate as superior metal-free catalysts for acetylene hydrochlorination

Journal Article


Abstract


  • N-Doped mesoporous carbon extrudate with a major quaternary N species has been successfully prepared through direct carbonization of wheat flour/gluten with silica, which is a cheap and convenient method for scale-up production approach. The obtained carbon extrudate metal-free catalyst enables highly efficient production of vinyl chloride monomer through acetylene hydrochlorination, with a superior catalytic performance and excellent stability ( > 85% conversion and vinyl chloride selectivity over 99% at 220 °C).

Authors


  •   Lan, Guojun (external author)
  •   Wang, Yan (external author)
  •   Qiu, Yiyang (external author)
  •   Wang, Xiaolong (external author)
  •   Liang, Ji
  •   Han, Wenfeng (external author)
  •   Tang, Haodong (external author)
  •   Liu, Huazhang (external author)
  •   Liu, Jian (external author)
  •   Li, Ying (external author)

Publication Date


  • 2018

Citation


  • Lan, G., Wang, Y., Qiu, Y., Wang, X., Liang, J., Han, W., Tang, H., Liu, H., Liu, J. & Li, Y. (2018). Wheat flour-derived N-doped mesoporous carbon extrudate as superior metal-free catalysts for acetylene hydrochlorination. Chemical Communications, 54 (6), 623-626.

Scopus Eid


  • 2-s2.0-85040950517

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/2961

Has Global Citation Frequency


Number Of Pages


  • 3

Start Page


  • 623

End Page


  • 626

Volume


  • 54

Issue


  • 6

Place Of Publication


  • United Kingdom

Abstract


  • N-Doped mesoporous carbon extrudate with a major quaternary N species has been successfully prepared through direct carbonization of wheat flour/gluten with silica, which is a cheap and convenient method for scale-up production approach. The obtained carbon extrudate metal-free catalyst enables highly efficient production of vinyl chloride monomer through acetylene hydrochlorination, with a superior catalytic performance and excellent stability ( > 85% conversion and vinyl chloride selectivity over 99% at 220 °C).

Authors


  •   Lan, Guojun (external author)
  •   Wang, Yan (external author)
  •   Qiu, Yiyang (external author)
  •   Wang, Xiaolong (external author)
  •   Liang, Ji
  •   Han, Wenfeng (external author)
  •   Tang, Haodong (external author)
  •   Liu, Huazhang (external author)
  •   Liu, Jian (external author)
  •   Li, Ying (external author)

Publication Date


  • 2018

Citation


  • Lan, G., Wang, Y., Qiu, Y., Wang, X., Liang, J., Han, W., Tang, H., Liu, H., Liu, J. & Li, Y. (2018). Wheat flour-derived N-doped mesoporous carbon extrudate as superior metal-free catalysts for acetylene hydrochlorination. Chemical Communications, 54 (6), 623-626.

Scopus Eid


  • 2-s2.0-85040950517

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/2961

Has Global Citation Frequency


Number Of Pages


  • 3

Start Page


  • 623

End Page


  • 626

Volume


  • 54

Issue


  • 6

Place Of Publication


  • United Kingdom