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Kinetics of phase decomposition in MAX phases - A comparative diffraction study

Journal Article


Abstract


  • The susceptibility of MAX phases to thermal dissociation at 1300-1550 °C in high vacuum has been studied using in-situ neutron diffraction. Above 1400 °C, MAX phases decomposed to binary carbide (e.g. TiC x) or binary nitride (e.g. TiN x), primarily through the sublimation of A-elements such as Al or Si, which results in a porous surface layer of MXx being formed. Positive activation energies were determined for the decomposition of MAX phases except for Ti 3AlC 2 where negative activation energy of 71.9 kJ mol -1 was obtained due to formation of fine pores on TiC x. The kinetics of isothermal phase decomposition at 1550 °C was modelled using a modified Avrami equation. An Avrami exponent (n) of < 1.0 was determined, indicative of the highly restricted diffusion of Al or Si between the channels of M 6X octahedra. The characteristics of thermal stability and phase transition are discussed.

Publication Date


  • 2011

Citation


  • Low, I. M. & Pang, W. K. (2011). Kinetics of phase decomposition in MAX phases - A comparative diffraction study. Journal of the Australian Ceramic Society, 47 (2), 16-22.

Scopus Eid


  • 2-s2.0-84855905919

Has Global Citation Frequency


Number Of Pages


  • 6

Start Page


  • 16

End Page


  • 22

Volume


  • 47

Issue


  • 2

Place Of Publication


  • Australia

Abstract


  • The susceptibility of MAX phases to thermal dissociation at 1300-1550 °C in high vacuum has been studied using in-situ neutron diffraction. Above 1400 °C, MAX phases decomposed to binary carbide (e.g. TiC x) or binary nitride (e.g. TiN x), primarily through the sublimation of A-elements such as Al or Si, which results in a porous surface layer of MXx being formed. Positive activation energies were determined for the decomposition of MAX phases except for Ti 3AlC 2 where negative activation energy of 71.9 kJ mol -1 was obtained due to formation of fine pores on TiC x. The kinetics of isothermal phase decomposition at 1550 °C was modelled using a modified Avrami equation. An Avrami exponent (n) of < 1.0 was determined, indicative of the highly restricted diffusion of Al or Si between the channels of M 6X octahedra. The characteristics of thermal stability and phase transition are discussed.

Publication Date


  • 2011

Citation


  • Low, I. M. & Pang, W. K. (2011). Kinetics of phase decomposition in MAX phases - A comparative diffraction study. Journal of the Australian Ceramic Society, 47 (2), 16-22.

Scopus Eid


  • 2-s2.0-84855905919

Has Global Citation Frequency


Number Of Pages


  • 6

Start Page


  • 16

End Page


  • 22

Volume


  • 47

Issue


  • 2

Place Of Publication


  • Australia